Effects of HDDR process on structure and magnetic properties of Nd(Fe,Ti)12Nδ prepared by mechanical alloying

被引：0
|
作者：
Cui, B.Z. [1 ]
Sun, X.K. [1 ]
Zhao, X.G. [1 ]
Liu, W. [1 ]
Xiao, Q.F. [1 ]
Zhao, T. [1 ]
Zhang, Z.D. [1 ]
Sui, Y.C. [1 ]
机构：
[1] Chinese Acad of Sciences, Shenyang, China
来源：
Acta Metallurgica Sinica (English Letters) | 1998年 / 11卷 / 01期
关键词：
Coercive force - Desorption - High temperature effects - Hydrogenation - Magnetic properties - Mechanical alloying - Phase transitions;
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摘要：
The effects of the hydrogenation-disproportionation-desorption-recombination (HDDR) process on the structure and the magnetic properties of the mechanical alloying (MA) prepared Nd8Fe84Ti8 alloy and its nitride counterpart have been studied in detail. It has been found that Nd(Fe, Ti)12Hδ is formed in the temperature range from 30 to 550 °C. The disproportionation is ready to start at 550 °C and is complete at 960 °C. The desorption and the recombination are almost synchronized. The phase of Nd(Fe, Ti)7 is formed at 750 °C during the HDDR treatment. With increasing temperature of HDDR process, the metastable structure of TbCu7 type is gradually transformed into the structure of ThMn12 type. The intrinsic coercivity and the maximum magnetic energy product increase with increasing temperature of HDDR process.
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页码：68 / 78
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