Sintering characteristics, electrical conductivity and thermal properties of La-doped ceria powders

被引:0
|
作者
Suda, Eisaku [1 ]
Pacaud, Bernard [1 ]
Mori, Masashi [2 ]
机构
[1] R and D Department, ANAN KASEI Co. Ltd., 210-51, Ohgata, Anan, Tokushima 774-0022, Japan
[2] Materials Science Research Laboratory, Central Research Institute of Electric Power Industry, 2-6-1 Nagasaka, Yokosuka, Kanagawa 240-0196, Japan
来源
Journal of Alloys and Compounds | 1600年 / 408-412卷
关键词
Ce1-xLaxO2-δ (0 &le x &le 0.4) powders have been synthesized through a newly devised heat-treatment process in the co-precipitation method; and their sintering characteristics; electrical conductivity and thermal properties have been examined as potential electrolytes in the intermediate-temperature solid oxide fuel cells. Sintering characteristics of the samples have a tendency to decrease with increasing dopant content of La. A relative density ≥94% was obtained after heating at 1500 °C for 2 h for Ce0.9La0.1O1.95 and at 1600 °C for 10 h for Ce0.8La0.2O1.9. Electrical conductivies at 500 °C and thermal expansion coefficients (50-500 °C) in air for the sintered samples were 3.48 × 10 -3 S/cm and 11.5 × 10-6 °C-1 for Ce0.9La0.1O1.95; and 3.71 × 10 -3 S/cm and 11.7 × 10-6 °C-1 for Ce0.8La0.2O1.9. © 2005 Elsevier B.V. All rights reserved;
D O I
暂无
中图分类号
学科分类号
摘要
Conference article (CA)
引用
收藏
页码:1161 / 1164
相关论文
共 50 条
  • [41] Ionic conductivity and thermodynamic stability of La-doped BIMEVOX
    Chmielowiec, J.
    Pasciak, G.
    Bujlo, P.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 451 (1-2) : 676 - 678
  • [42] Temperature stability and electrical properties in La-doped KNN-based ceramics
    Lv, Xiang
    Wu, Jiagang
    Zhu, Jianguo
    Xiao, Dingquan
    Zhang, Xi-xiang
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2018, 101 (09) : 4084 - 4094
  • [43] Magnetic and Electrical Properties of Low La-doped NiCuZnFe Nanocrystalline Ferrite Films
    Yang Hangfu
    Zhang Pengyue
    Wu Qiong
    Cui Yujian
    Tang Peisong
    Ge Hongliang
    RARE METAL MATERIALS AND ENGINEERING, 2012, 41 : 515 - 518
  • [44] Oxygen defects related to electrical properties of La-doped BaTiO3
    Itoh, J
    Park, DC
    Ohashi, N
    Sakaguchi, I
    Yashima, I
    Haneda, H
    Tanaka, J
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (6A): : 3798 - 3803
  • [45] Catalytic oxidation of methane over Zr and La-doped ceria nanocatalysts
    Zimicz, M. G.
    Toscani, L. M.
    Prado, A.
    Costilla, I. O.
    Soldati, A. L.
    Aristizabal, M. E.
    Larrondo, S. A.
    Prado, F. D.
    MOLECULAR CATALYSIS, 2025, 573
  • [46] Electrical properties of samaria-doped ceria electrolytes from highly active powders
    Ding, Dong
    Liu, Beibei
    Gong, Mingyang
    Liu, Xingbo
    Xia, Changrong
    ELECTROCHIMICA ACTA, 2010, 55 (15) : 4529 - 4535
  • [47] Sintering behaviour and ionic conductivity of yttria-doped ceria
    Vanherle, J
    Horita, T
    Kawada, T
    Sakai, N
    Yokokawa, H
    Dokiya, M
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1996, 16 (09) : 961 - 973
  • [48] Sintering Behaviour and Ionic Conductivity of Yttria-Doped Ceria
    Natl. Inst. of Mat. and Chem. Res., 1-1 Higashi, Tsukuba Science City, 305 Ibaraki, Japan
    不详
    J. Eur. Ceram. Soc., 9 (961-973):
  • [49] Electrical and ionic conductivity of Gd-doped ceria
    Wang, SR
    Kobayashi, T
    Dokiya, M
    Hashimoto, T
    SOLID OXIDE FUEL CELLS (SOFC VI), 1999, 99 (19): : 193 - 200
  • [50] Electrical and ionic conductivity of Gd-doped ceria
    Wang, SR
    Kobayashi, T
    Dokiya, M
    Hashimoto, T
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (10) : 3606 - 3609