Vanadium-catalyzed cross-coupling reactions of alkyl halides with aryl grignard reagents

被引：0
|
作者：
Yasuda, Shigeo [1 ]
Yorimitsu, Hideki [1 ]
Oshima, Koichiro [1 ]
机构：
[1] Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
来源：
Bulletin of the Chemical Society of Japan | 2008年 / 81卷 / 02期
关键词：
Vanadium(III) chloride catalyzed cross-coupling reactions of alkyl halides with arylmagnesium bromides. Various arylmagnesium bromides; except for an ortho-substituted arylmagnesium reagent; could be used for the reaction. Among alkyl halides tested; cyclohexyl halides and primary alkyl halides were good substrates. The reactions likely proceed via carbon-centered radical intermediates. ©2008 The Chemical Society of Japan;
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页码：287 / 290
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