Molecular rectifier based on [4-[(N-(2-thiolethyl), N'-methyl)amino]phenyl]tricyanoethene (TAPE)

被引：0
|
作者：
Lu, Yin-Xiang [1 ]
Lan, Bi-Jian [1 ]
Ji, Xin [1 ]
Jin, Lan [1 ]
Xu, Wei [1 ]
机构：
[1] Department of Materials Science, Fudan University, Shanghai 200433, China
来源：
Gongneng Cailiao/Journal of Functional Materials | 2006年 / 37卷 / 10期
关键词：
Electric potential - Electric properties - Electrodes - Fourier transform infrared spectroscopy - Monolayers - Scanning tunneling microscopy - Self assembly;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
[4-[(N-(2-thiolethyl), N'-methyl)amino]phenyl]tricyanoethene (TAPE), a kind of conjugated organic molecule with sulfhydryl group, was synthesized. Molecular rectifier Au/TAPE/Au (nanoparticle) was prepared by self-assembled monolayer (SAM) method. The current-voltage (I-V) character was measured by scanning tunneling microscopy (STM), a maximum rectification ratio of 22.7 was obtained at the bias voltage of ± 0.95 V. The electrical property of the monolayer, fore-and-aft top electrode's preparation process, was studied. The organic monolayer was characterized by grazing incidence FTIR.
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页码：1617 / 1619
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