Molecular structure of aminoguanidine sulfate monohydrate

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作者：

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China ^{[1
]}

不详 ^{[2
]}

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来源：

J Beijing Inst Technol Engl Ed | 2006年 / 4卷 / 473-477期

关键词：

Crystal structure - Decomposition - Dehydration - Electrostatics - Heating - Hydrogen bonds - Melting - Single crystals - Thermoanalysis - X ray diffraction analysis;

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摘要：

The single crystal of aminoguanidine sulfate monohydrate[(AG)2SO4&middotH2O] is obtained and its structure is determined by X-ray diffraction analysis. The compound crystallizes in orthorhombic system with space group Pnma and the empirical formula C2H16N8O5S. The unit cell parameters are as follows: a=0.6759 (2) nm, b=1.4131 (5) nm, c=1.1650 (4) nm, V=1.1128 (6) nm3, Z=4, Dc=1.578 g/cm3, F (000)=560, s=1.069, μ(MoKα)=0.318 mm-1. The final R and wR are 0.0312 and 0.0833, respectively. The title compound is an ionic compound and its structure unit consists of two aminoguanidium cations, one sulfate anion and one crystal water molecule, which are interconnected by electrostatic forces and hydrogen bonds into net structure, making the title compound very stable. Under a linear heating rate, the thermal decomposition processes of (AG)2SO4&middotH2O have one endothermal dehydration stage, one melting process and one exothermic decomposition stage at 50-400°C, and can evolve abundant gas products.

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[21] CRYSTAL AND MOLECULAR STRUCTURE OF CHLOROGLYCYLGLYCINATOCOPPER (II) MONOHYDRATE
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NAKAO, Y
NAKAHARA, A
CHEMISTRY LETTERS, 1972, (02) : 123 - +
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ACTA CRYSTALLOGRAPHICA, 1963, 16 (07): : 596 - &
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[27] THE CRYSTAL-STRUCTURE OF DI-L-PHENYLALANINE SULFATE MONOHYDRATE
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[28] Experimental and Computational Studies on Aminoguanidine Free Base, Monocation and Dication, Part I: The Crystal and Molecular Structure of Aminoguanidine Monohydrochloride and the ab Initio Structure of the Endiamine Tautomer of Aminoguanidine Free Base
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[29] Experimental and computational studies on aminoguanidine free base, monocation and dication .1. The crystal and molecular structure of aminoguanidine monohydrochloride and the ab initio structure of the endiamine tautomer of aminoguanidine free base
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[30] LITHIUM SULFATE MONOHYDRATE DEHYDRATION
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