Precision control of monomer sequences in vinyl copolymers

被引：0
|
作者：
Satoh, Kotaro [1 ]
Kamigaito, Masami [1 ]
机构：
[1] Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Japan
来源：
Kobunshi | 2014年 / 63卷 / 10期
关键词：
Atom transfer radical polymerization - Free radical polymerization - Living polymerization - Monomers;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
This short review describes several recent approaches to precision control of monomer sequences in vinyl copolymers mainly using radical polymerizations. They include radical chain copolymerization of a specific pair of monomers for generating 1:2 or ABB-monomer sequences in addition to conventional 1:1 alternating ones, sequential addition of vinyl monomers into the living radical polymers or oligomers, and metathesis polymerization for constructing equivalent structures of vinyl copolymers. Such precision control will contribute to construction of a novel polymer that may work as not only a bulk material but also a functional single macromolecule.
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页码：715 / 717
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