Doppler-free two-photon excitation spectroscopy and the Zeeman effect in the channel three region of C6H6

被引：0

作者：

Dae, Youl Baek ^{[1
]}

Chen, JinHai ^{[1
]}

Wang, Jinguo ^{[1
]}

Doi, Atsushi ^{[1
]}

Kasahara, Shunji ^{[1
]}

Baba, Masaaki ^{[2
]}

Kato, Hajime ^{[1
]}

机构：

[1] Molecular Photoscience Research Center, Kobe University, Nada-ku, Kobe 657-8501

[2] Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502

来源：

Bulletin of the Chemical Society of Japan | 2006年 / 79卷 / 01期

关键词：

Doppler-free two-photon excitation spectra and the Zeeman effects for the 1021401 and 10 11401 bands; whose vibrational excess energies are 3412 and 2492 cm-1; respectively; of the S1 1B2u ← S0 1A1g transition in gaseous benzene-h6 have been measured. Rotationally resolved lines up to a rotational excess energy of 945 cm-1 in the 1011401 band; whose excess energy is isoenergetic with the one of the 102140 1 band at low J; have been observed. The density of perturbation is observed to increase around the K = 0 and K = J levels in the 10 11401 band as the rotational energy increases; but line broadening is not observed. It was reported that only the K = 0 lines at low J and the K = J lines at high J were observed as a sharp line and the rest was washed out by broadening in the 10214 01 band. The assignments are confirmed by the Zeeman spectra. The character and magnitude of Zeeman splittings in both bands could be understood as originating from the electronic orbital angular momentum arising from a mixing of the S1 1B2u and S2 1B1u states via J-L coupling. The levels of the S 1 1B2u state are found not to be mixed with a triplet state by the Zeeman effect. © 2006 The Chemical Society of Japan;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Journal article (JA)

引用

页码：75 / 79

共 50 条

[21] Doppler-free two-photon excitation spectroscopy and the Zeeman effect of the 1401 band of the S1 1B2u←S0 1A1g transition of benzene-d6
Wang, JG
Doi, A
Kasahara, S
Kato, H
Baba, M
JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (18): : 9188 - 9190
[22] Doppler-free two-photon excitation of Lyman-α fluorescence for the diagnostics of magnetically confined fusion plasmas
Voslamber, D
REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (06): : 2334 - 2352
[23] LIFETIMES OF SINGLE ROTATIONAL STATES IN THE CHANNEL 3 REGION OF C6H6
SCHUBERT, U
RIEDLE, E
NEUSSER, HJ
SCHLAG, EW
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (11): : 6182 - 6189
[24] Doppler-free two-photon absorption spectroscopy and the Zeeman effect of the A 1B2u←X 1A1g1401101 band of benzene
Misono, M
Wang, J
Ushino, M
Okubo, M
Kato, H
Baba, M
Nagakura, S
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (01): : 162 - 171
[25] Doppler-free two-photon absorption spectroscopy of rovibronic transition of naphthalene calibrated with an optical frequency comb
Nishiyama, A.
Nakashima, K.
Matsuba, A.
Misono, M.
JOURNAL OF MOLECULAR SPECTROSCOPY, 2015, 318 : 40 - 45
[26] Doppler-Free Two-Photon Cavity Ring-Down Spectroscopy of a Molecular Vibrational Overtone Transition
Zhao, Gang
Bailey, D. Michelle
Fleisher, Adam J.
Hodges, Joseph T.
Lehmann, Kevin K.
2021 CONFERENCE ON LASERS AND ELECTRO-OPTICS (CLEO), 2021,
[27] SUB-DOPPLER HIGH-RESOLUTION SPECTRA OF C6H6 - ANOMALOUS RESULTS IN THE CHANNEL 3 REGION
RIEDLE, E
NEUSSER, HJ
SCHLAG, EW
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (25): : 4847 - 4850
[28] Electric field measurements in discharges by Doppler-free two-photon laser Stark spectroscopy of atomic hydrogen
Booth, JP
Derouard, J
Fadlallah, M
Cabaret, L
Pinard, J
OPTICS COMMUNICATIONS, 1996, 132 (3-4) : 363 - 370
[29] Pulsed Doppler-free two-photon excitation of hydrogen Lyman-α fluorescence in magnetically confined fusion plasmas
Voslamber, D
Seidel, J
SPECTRAL LINE SHAPES, 2002, 645 : 52 - 59
[30] Measurement of the deuterium/tritium fuel mixture in magnetic confinement fusion plasmas by Doppler-free two-photon spectroscopy
Voslamber, D.
Seidel, J.
Review of Scientific Instruments, 1999, 70 (1 pt 2): : 928 - 931

← 1 2 3 4 5 →