Block copolymerization of 2,2-dimethyltrimethylene carbonate with adipic anhydride catalyzed by lanthanum tris(2,6-di-tert-butyl-4-methylphenolate)

被引：0

作者：

Ling J. ^{[1
]}

Ren S. ^{[1
]}

Shen Z. ^{[1
]}

机构：

[1] Key Laboratory of Macromolecular Synthesis and Functionalization of the Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University

来源：

E-Polymers | 2010年

关键词：

D O I：

10.1515/epoly.2010.10.1.270

中图分类号：

学科分类号：

摘要：

Tetrahydrofuran-soluble block copolymer of 2,2-dimethyltrimethylene carbonate with adipic anhydride [poly(DTC-b-AA)] containing 64.7/35.3 DTC/AA in molar ratio with Mn of 12.3×104 and M w/Mn of 1.64 was synthesized by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) catalyst at 25 °C in 32 min. The copolymer was characterized by SEC, 1H NMR and DSC. Copolymers with AA block from 8.5 % to 50.8 % were prepared by changing the solvent and feeding ratio of DTC/AA.

引用

共 50 条

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