Synthesis of novel siloxane room temperature liquid crystalline

被引:0
|
作者
Wu, Zheng-Long [1 ]
Liao, Chien-Tung [1 ]
Lee, Jiunn-Yih [1 ]
机构
[1] Department of Material and Science Engineering, National Taiwan University of Science and Technology, Taipei, 106, Taiwan
来源
Journal of Technology | 2012年 / 27卷 / 01期
关键词
Differential scanning calorimetry - Liquid crystals - Stereochemistry - X ray diffraction;
D O I
暂无
中图分类号
学科分类号
摘要
This article's goal was to analyze the synthesis of room temperature liquid crystal materials with low molar mass organosiloxane. The structures contain 4'-hydroxybiphenyl-4-yl 4-hydroxybenzoate core and chiral butyl 2-hydroxypropanoate unit, and organosiloxane on the end of the achiral molecules. A few novel series of room temperature compounds were synthesized, and the mesophases exhibited by them were compared. The mesophases under discussion were investigated using polarizing microscopy, differential scanning calorimetry, and X-ray diffraction. The substituent had a strong influence in reducing the clearing temperatures and increasing temperature range. The influence of the molecular structure on the occurrence of the SmC* phase was investigated in the article.
引用
收藏
页码:37 / 44
相关论文
共 50 条
  • [41] Lyotropic liquid-crystalline gel formation in a room-temperature ionic liquid
    Firestone, MA
    Dzielawa, JA
    Zapol, P
    Curtiss, LA
    Seifert, S
    Dietz, ML
    LANGMUIR, 2002, 18 (20) : 7258 - 7260
  • [42] SYNTHESIS OF CRYSTALLINE ZINC FERRITE NEAR ROOM-TEMPERATURE
    UEDA, M
    SHIMADA, S
    INAGAKI, M
    JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (12) : 1199 - 1201
  • [43] Liquid crystalline copper(i) complexes with bright room temperature phosphorescence
    Gimenez, Raquel
    Crespo, Olga
    Diosdado, Beatriz
    Elduque, Anabel
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (19) : 6552 - 6557
  • [44] Room temperature liquid crystalline perylene diester benzimidazoles with extended absorption
    Wicklein, Andre
    Muth, Mathis-Andreas
    Thelakkat, Mukundan
    JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (39) : 8646 - 8652
  • [45] High hole mobility in room temperature discotic liquid crystalline tetrathienoanthracenes
    Bala, Indu
    De, Joydip
    Gupta, Santosh Prasad
    Singh, Harpreet
    Pandey, Upendra Kumar
    Pal, Santanu Kumar
    CHEMICAL COMMUNICATIONS, 2020, 56 (42) : 5629 - 5632
  • [46] Liquid crystalline compounds with various rigid siloxane frameworks
    Ahsan, Md. Shameem
    Sasaki, Shintaro
    Kawakami, Yusuke
    REACTIVE & FUNCTIONAL POLYMERS, 2007, 67 (11): : 1200 - 1210
  • [47] Room temperature discotic liquid crystalline thin films of hexa-peri-hexabenzocoronene:: Synthesis and optoelectronic properties
    Liu, CY
    Fechtenkötter, A
    Watson, MD
    Müllen, K
    Bard, AJ
    CHEMISTRY OF MATERIALS, 2003, 15 (01) : 124 - 130
  • [48] Optimization of room temperature ionic liquid synthesis process
    Shenzhen Key Laboratory of Special Functional Materials, School of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
    Shenzhen Daxue Xuebao (Ligong Ban), 2007, 4 (414-417):
  • [49] Room temperature synthesis in liquid ammonia of tin sulfide
    Shaw, GA
    Parkin, IP
    MAIN GROUP METAL CHEMISTRY, 1996, 19 (08): : 499 - 502
  • [50] Synthesis of sodalite in room-temperature ionic liquid
    Ma, YC
    Xu, YP
    Wang, SJ
    Wang, BC
    Tian, ZJ
    Yu, JY
    Lin, LW
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2006, 27 (04): : 739 - 741