Elucidating the influence of side chains on the self-assembly of semi-flexible mesogens

被引：0
|
作者：
Gearba, Raluca I. [1 ,4 ]
Anokhin, Denis V. [2 ,3 ]
Ivanov, Dimitri A. [1 ,3 ]
机构：
[1] Inst Sci Mat Mulhouse, CNRS UMR 7361, 15 Rue Jean Starcky, F-68057 Mulhouse, France
[2] Lomonosov Moscow State Univ, Fac Chem, GSP-1,1-3 Leninskie Gory, Moscow 119991, Russia
[3] Natl Univ Sci & Technol MISIS, Lab Struct Methods Mat Invest, Leninskiy Prospekt 4, Moscow 119049, Russia
[4] Univ Texas Austin, Texas Mat Inst, 2501 Speedway, Austin, TX 78712 USA
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 61卷 / 02期
关键词：
COLUMNAR; ORGANIZATION; MOLECULES; SYSTEMS;
D O I：
10.1039/d4cc05421k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the development of functional materials, side chains are traditionally incorporated into the primary chemical structure to induce liquid-crystalline behavior or to enhance solubility for improved processability. However, emerging evidence suggests that side chains play a far more complex role. This study presents a case of a double helical supramolecular structure formed by star-shaped mesogens in the absence of specific interactions. The molecular conformation is primarily dictated by the self-assembly of the side chains, introducing a new organizational paradigm for semiflexible low-molecular-weight mesogens.
引用
收藏
页码：282 / 285
页数：4
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