3Y-TZP ceramics simulation of the fluorescence properties of natural teeth by doping Eu2+

被引:0
|
作者
Shi, Lianshui [1 ,2 ]
Zhao, Fujian [2 ]
Chen, Weifan [3 ]
Zhou, Xuezhen [3 ]
Wang, Zhenshi [2 ]
Li, Yongxiu [1 ]
机构
[1] Research Center for Rare Earths & Micro/Nano Functional Materials, Nanchang University, Nanchang, China
[2] Department of Prosthodontics, Stomatological Hospital Affiliated to Nanchang University, Nanchang, China
[3] School of Materials Science and Engineering, Nanchang University, Nanchang, China
来源
关键词
Scanning electron microscopy - Cytotoxicity - Emission spectroscopy - Europium compounds - Crystal structure - X ray diffraction - Zirconia;
D O I
10.3969/j.issn.1001-9731.2015.18.015
中图分类号
学科分类号
摘要
Eu2+-doped 3Y-TZP dental bioceramic was prepared by immersing the presintering 3Y-TZP in Eu(NO3)3solution, followed with calcination under reducing atmosphere. The surface microstructure, phase constitution, fluorescence spectrum and cytotoxicity were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM), fluorescence spectrometer and MTT test. The results showed that Eu2+-doped 3Y-TZP presented a densification morphology and the average grain size was 450 nm. There were no other crystal structure other than t-ZrO2was found. The emission spectrum excited by 365 nm showed a characteristic blue broad band with the peak at about 470 nm, which corresponded to 4f65d1→4f7(8S7/2) transition of Eu2+. This emission spectrum was similar to the natural tooth which can be used to simulation of the fluorescence emission of natural teeth. The cytotoxicity grade of Eu2+-doped 3Y-TZP was I, which can be used for clinical with biological safety. © 2015, Journal of Functional Materials. All right reserved.
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页码:18074 / 18077
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