Analysis of PAHs formation with oxygenated fuels based on ROP

被引：0
|
作者：
Wang, Zhong [1 ]
Li, Mingdi [1 ]
Li, Lilin [1 ,2 ]
Chen, Lin [1 ]
Xu, Guangju [1 ]
机构：
[1] School of Automobile and Traffic Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China
[2] Department of Mechanical Engineering, Henan Institute of Engineering, Zhengzhou, Henan 450000, China
来源：
Jiangsu Daxue Xuebao (Ziran Kexue Ban)/Journal of Jiangsu University (Natural Science Edition) | 2012年 / 33卷 / 02期
关键词：
Ethanol - Shock tubes - Benzene - Free radicals - Ethers - Fuels - Naphthalene;
D O I：
10.3969/j.issn.1671-7775.2012.02.007
中图分类号：
O62 [有机化学]; TQ [化学工业];
学科分类号：
070303 ; 0817 ; 081704 ;
摘要：
According to shock tube model, the formation of benzene, naphthalene, phenanthrene and pyrene was analyzed by simulating their production rate through ROP to investigate the PAHs formation paths of oxygenated fuels. The results show that the magnitude of production rate of ethanol, DME and DMC is orderly decreased with initial equivalent ratio of 1.0 and temperature of 1600 K. The polymerization of propargyl is the main path for benzene formation. Naphthalene is formed mainly through second HACA reaction and combination reaction of phenyl and vinyl acetylene. Phenanthrene and pyrene are mainly formed through HACA reaction. H and OH radicals play an important role in the oxidation of PAHs. In the reaction of third body M, ethanol can inhibit PAHs formation. DME has slight effect on PAHs formation, while DMC can promote PAHs formation.
引用
收藏
页码：155 / 159
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