Reactivity of N-(isocyanoimino)triphenylphosphorane toward group 13 Lewis acids

被引：0

作者：

Tang, Beili ^{[1
]}

Ju, Shaoying ^{[1
]}

Yan, Weili ^{[2
]}

Chen, Ting ^{[1
]}

Stephan, Douglas W. ^{[1
,3
]}

Wu, Yile ^{[1
]}

机构：

[1] Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Pinghu Inst Adv Mat, Pinghu 314200, Zhejiang, Peoples R China

[3] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 88期

基金：

中国国家自然科学基金;

关键词：

BESTMANN YLIDE; POLYMERIZATION; HYDROGENATION; DERIVATIVES; BORON;

D O I：

10.1039/d4cc04490h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The species Ph3PNNC 1 reacts with the group 13 Lewis acids E(C6F5)(3) (E = B or Al), HB(C6F5)(2), ClAl(C6F5)(2) and ECl3 (E = Ga or In) to give the Lewis acid-base adduct Ph3PNNCB(C6F5)(3) 2, the zwitterionic product (Ph3PNH)B(C6F5)(2)CNB(C6F5)(2)H 3, the chelated salts [(Ph3PNNC(CN)NPPh3)ER2][EX2R2] (E = Al, R = X = C6F5, 4; E = Al, R = C6F5, X = Cl, 5; E = Ga, R = X = Cl, 6), and the neutral species [(Ph3PNNC(CN)NPPh3)InCl3] 7. The nature of these variations in reactivity are rationalized and the potential utility considered.

引用

页码：12932 / 12935

页数：4

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