Recent Developments in the Electrocatalytic Reduction of CO2 in Acidic Environments

被引：0
|
作者：
Sun Y. [1 ]
Xu S. [1 ]
Zou J. [1 ]
Wu Z. [1 ]
Xie S. [1 ]
机构：
[1] State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), College of Chemistry and Ch
来源：
Cailiao Daobao/Materials Reports | 2024年 / 38卷 / 08期
基金：
中国国家自然科学基金;
关键词：
acidic electrolytes; carbon dioxide; electrocatalysis; reduction;
D O I：
10.11896/cldb.23040216
中图分类号：
学科分类号：
摘要：
Electrocatalytic conversion of CO2 into high-value chemicals and fuels by renewable energy provides a viable approach to the global climate change and energy crisis,and its development has great potential for practical production‧ At present,most of the basic and neutral reaction systems studied,CO2 is liable to interact with hydroxide (OH-)to form carbonate or bicarbonate,resulting in CO2 loss,lowering the energy conversion efficiency and stability of the reaction system‧ The above problems will be solved by the research and development of electrocatalytic CO2 reduction reaction (CO2 RR)in acid‧ This review has shed light on the effects of reaction device,catalyst,reaction microenvironment on the performance of CO2 RR and the microscopic reaction mechanism systematically in acidic CO2 RR‧ Finally,foresight tactics are put forward for catalyst design,reaction mechanism research,reaction microenvironment regulation,and reactor design and optimization in acidic CO2 RR‧ © 2024 Cailiao Daobaoshe/ Materials Review. All rights reserved.
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共 54 条
  • [31] Zheng T, Zhang M, Wu L, Et al., Nature Catalysis, 5, (2022)
  • [32] Liu Z, Yan T, Shi H, Et al., ACS Applied Materials & Interfaces, 14, 6, (2022)
  • [33] Bondue C J, Graf M, Goyal A, Et al., Journal of the American Chemical Society, 143, 1, (2021)
  • [34] Sheng X, Ge W, Jiang H, Et al., Advanced Materials, 34, 38, (2022)
  • [35] Pan B, Fan J, Zhang J, Et al., ACS Energy Letters, 7, 12, (2022)
  • [36] Boutin E, Merakeb L, Ma B, Et al., Chemical Society Reviews, 49, 16, (2020)
  • [37] Meshitsuka S, Ichikawa M, Tamaru K., Journal of the Chemical Society Chemical Communications, 5, (1974)
  • [38] Lieber C M, Lewis N S., Journal of the American Chemical Society, 106, 17, (1984)
  • [39] Schneider J, Jia H, Muckerman J T, Et al., Chemical Society Reviews, 41, 6, (2012)
  • [40] Han N, Wang Y, Ma L, Et al., Chem, 3, 4, (2017)
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