Features of magnetic structure and properties of ceramics (1-x)Pb(Fe1/2Nb1/2)o3-xPb(Fe2/3W1/3)o3

被引：0
|
作者：
Glazunova, E. V. [1 ]
Kubrin, S. P. [1 ]
Shilkina, L. A. [1 ]
Lis, O. N. [2 ]
Nagaenko, A. V. [3 ]
Verbenko, I. A. [1 ]
Kichanov, S. E. [2 ]
Rutkauskas, A. V. [2 ]
Reznichenko, L. A. [1 ]
机构：
[1] Southern Fed Univ, Res Inst Phys, Rostov Na Donu, Russia
[2] Joint Inst Nucl Res, Lab Neutron Phys IM Frank, Dubna, Russia
[3] Southern Fed Univ, Inst High Technol & Piezo Tech, Rostov Na Donu, Russia
来源：
FERROELECTRICS | 2024年 / 618卷 / 06期
关键词：
multiferroics; solid-phase synthesis; magnetic moment; Neel temperature; MULTIFERROICS;
D O I：
10.1080/00150193.2024.2305576
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We studied solid solutions of the system (1-x)PbFe1/2Nb1/2O3 - xPbFe(2/3)W(1/3)O(3) using X-ray and Neuron diffraction, and M & ouml;ssbauer spectroscopy. To obtain ceramics, we used the method of two-stage solid-phase synthesis and sintering according to the conventional ceramic technology. Pure solid solutions of the (1-x)PbFe1/2Nb1/2O3-xPbFe(2/3)W(1/3)O(3) system were obtained. A deviation of the unit cell parameters from the Vegard rule was revealed, which indicates stratification of the structure into microregions differing in composition. The introduction of PbFe2/3W1/3O3 into the system led to partial ordering (clustering) of cations in the B position. An increase in magnetic moment with growing amount of PbFe2/3W1/3O3 was shown.
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页码：1374 / 1382
页数：9
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