Reducing corrosion and hydrogen gas release inside an alkaline zinc-air battery by employing ionic liquid

被引:1
|
作者
Deyab, M. A. [1 ]
Mohsen, Q. [2 ]
机构
[1] Egyptian Petr Res Inst EPRI, Nasr City, Cairo, Egypt
[2] Taif Univ, Coll Sci, Dept Chem, Taif, Saudi Arabia
关键词
Zinc-air battery; Corrosion; Hydrogen gas; Ionic liquid; Discharge capacity; Capacity retention; ELECTROCHEMICAL ENERGY-STORAGE; SULFURIC-ACID; CARBON-STEEL; MILD-STEEL; INHIBITION; PASSIVATION; SURFACTANT; BEHAVIOR; PERFORMANCE; OPERATION;
D O I
10.1016/j.electacta.2024.145207
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Zn-air batteries are a promising route that might be used in a range of energy sectors. Significant disadvantages, such as passive film and hydrogen gas evolution (HGE) in alkaline corrosive medium; restrict the possible usage of Zn-air batteries. To address these problems and increase the performance of zinc-air batteries, an ionic liquid (tris(2hydroxyethyl) hydroxymethylammonium methyl sulfate [IL]+[MS]-) has been used in this study. The usage of [IL]+[MS]- in 7.0 M KOH solution has a considerable effect on suppressing hydrogen gas creation, with an effectiveness of 86.2 %. Increasing the depth of the Bode-phase angle and the charge transfer resistance by adding [IL]+[MS]- also indicates a slower hydrogen gas production rate. The application of the [IL]+[MS]- additive improves the zinc-air battery's specific discharge capacity and capacity retention. To support these findings, SEM/EDX has been used to analyze the morphological features of Zn anodes in various electrolytes.
引用
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页数:8
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