Room-temperature synthesis of carbon polymer dots from biomass for advanced sensing and fluorescent applications

被引:2
|
作者
Lan, Lin [1 ]
Bao, Rui [1 ]
Kong, Xin [1 ]
Liu, Liang [1 ]
Wang, Jinsong [1 ]
Yi, Jianhong [1 ]
机构
[1] Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Kunming 650093, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Carbon polymer dots; Biomass precursors; Room-temperature synthesis; Visual sensing; Fluorescent inks; IONS;
D O I
10.1016/j.jece.2024.114514
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study presents a novel method for producing polymer dots (PDs) and carbon polymer dots (CPDs) from biomass waste through an environmentally friendly process. This process involves room-temperature oxidation/ polymerization and Schiff base reactions, which do not require external energy, making it both energy-efficient and eco-friendly. The CPDs developed in this study show outstanding Fe3+ detection capabilities, with a wide linear range (0-10 mu M) and a low detection limit of 0.34 mu M. Recovery rates in real sample tests range from 97 % to 103.2 %, with relative standard deviations between 0.63 % and 2.14 %. These findings highlight the method's sustainability, cost-effectiveness, and accuracy. Moreover, the CPDs exhibit reversible fluorescence when activated by ascorbic acid (AA), paving the way for their use in creating fluorescent inks and films with polyvinyl alcohol (PVA). This suggests significant potential for applications in visual sensing and detection.
引用
收藏
页数:10
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