A review of NCM cathode and interface characteristics in all-solid-state lithium-ion battery with sulfide electrolytes

被引:0
|
作者
Guo B. [1 ]
Jia L. [2 ]
Zhang X. [1 ,2 ]
机构
[1] College of Mechanical and Engineering, Shanghai Jiao Tong University, Shanghai
[2] Shanghai Yili New Energy Technology Co., Ltd., Shanghai
来源
Huagong Xuebao/CIESC Journal | 2024年 / 75卷 / 03期
关键词
all-solid-state lithium-ion battery; cathode∕electrolyte interfaces; NCM cathode; sulfide electrolytes;
D O I
10.11949/0438-1157.20231279
中图分类号
学科分类号
摘要
All-solid-state lithium-ion battery (ASSLB) with sulfide electrolyte is regarded as the most effective solution to the safety problems and energy density improvement of traditional liquid lithium-ion batteries. The cathode material largely determines the basic performance of all-solid-state lithium-ion batteries, as one of the main part of lithium-ion batteries. The NCM cathode material has attracted widespread attention due to its advantages of higher energy density, lower cost, and compatibility with sulfide electrolytes. However, NCM cathode materials have some imperfections, such as low safety and poor cycle stability, and there are still many problems to be solved at its contact interface with sulfide electrolyte. Therefore, the research on the structure and interface optimization of NCM cathode material is of great significance to improve the energy density and stability of lithium-ion batteries. This paper focuses on the research of the current mainstream NCM cathode materials and the matching research of interface problems with sulfide-based solid electrolytes, expounding the challenges, solutions and development opportunities of NCM cathode materials. Prospects are proposed for the further development and application of NCM cathodes. © 2024 Materials China. All rights reserved.
引用
收藏
页码:743 / 759
页数:16
相关论文
共 87 条
  • [11] Huang W P, Sun G P, Chen X, Et al., Research progress of LiNi<sub>x</sub>Co<sub>y</sub>Mn<sub>1-</sub>x-<sub>y</sub>O<sub>2</sub> ternary cathode materials, Shandong Chemical Industry, 50, 16, pp. 104-106, (2021)
  • [12] Ohzuku T, Makimura Y., Layered lithium insertion material of LiCo<sub>1∕3</sub>Ni<sub>1∕3</sub>Mn<sub>1∕3</sub>O<sub>2</sub> for lithium-ion batteries, Chemistry Letters, 30, 7, pp. 642-643, (2001)
  • [13] Wu C Y, Feng C Q, Zhang C F, Et al., Research progress in layered lithium nickel cobalt manganese oxide ternary cathode material, Battery Bimonthly, 52, 1, pp. 3-7, (2022)
  • [14] Cui S H, Wei Y, Liu T C, Et al., Optimized temperature effect of Li-ion diffusion with layer distance in Li(Ni<sub>x</sub>Mn<sub>y</sub>Co<sub>z</sub>)O<sub>2</sub> cathode materials for high performance Li-ion battery, ECS Meeting Abstracts, 2, (2016)
  • [15] Jiang M, Danilov D L, Eichel R A, Et al., A review of degradation mechanisms and recent achievements for Ni-rich cathode-based Li-ion batteries, Advanced Energy Materials, 11, 48, (2021)
  • [16] Xiao Z L, Zhou C F, Song L B, Et al., Research progress of ternary material NCM for nickel-rich lithium ion battery, Chemical Industry and Engineering Progress, 39, 1, pp. 216-223, (2020)
  • [17] Zhang B, Zhang P, Xiang X G, Et al., Study on effect of different cobalt content on properties of ternary cathode materials, Inorganic Chemicals Industry, 53, 11, pp. 91-94, (2021)
  • [18] Yu H J, Qian Y M, Otani M, Et al., Study of the lithium∕nickel ions exchange in the layered LiNi<sub>0.42</sub>Mn<sub>0.42</sub>Co<sub>0.16</sub>O<sub>2</sub> cathode material for lithium ion batteries: experimental and first-principles calculations, Energy & Environmental Science, 7, 3, pp. 1068-1078, (2014)
  • [19] Tian X L, Yi Y K, Fang B R, Et al., Design strategies of safe electrolytes for preventing thermal runaway in lithium ion batteries, Chemistry of Materials, 32, 23, pp. 9821-9848, (2020)
  • [20] Yuan K, Li N, Ning R Q, Et al., Stabilizing surface chemical and structural Ni-rich cathode via a non-destructive surface reinforcement strategy, Nano Energy, 78, (2020)