Improved sodium storage properties NaFePO4/C as cathode material for sodium-ion batteries

被引:0
|
作者
Munusami, V. [1 ]
Arutselvan, K. [2 ]
Vadivel, S. [3 ]
Govindasamy, S. [2 ]
机构
[1] RP Sarathy Inst Technol, Dept Mech Engn, Salem 636305, Tamil Nadu, India
[2] RP Sarathy Inst Technol, Dept Elect & Elect Engn, Salem 636305, Tamil Nadu, India
[3] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Sch Engn, Dept Phys, Chennai 602105, Tamil Nadu, India
关键词
HIGH-PERFORMANCE ELECTRODE; MARICITE NAFEPO4; SURFACE-AREA;
D O I
10.1007/s10854-024-13817-5
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Because of the plentiful supply of sodium, sodium ion batteries (SIBs) as one of the most promising technologies for affordable rechargeable batteries. Here, we outline an easy method for creating a NaFePO4@C hybrid composite cathode for SIBs. GCD, CV, and EIS tests have been conducted to study the samples' electrochemical and kinematic properties. It is confirmed that modest carbon doping can enhance the electrocatalytic activity of NaFePO4 (NFP). The resulting NFP@C nanocomposite as cathode material for SIBs displays good rate capability and lofty capacity (158.5 mAhg-1) retention after 50 cycles at 0.1C. The NaFePO4 and the carbon covering, which make it easier for the Na + ion and electron to access the material quickly during the process of charging and discharging, respectively, are responsible for the good electrochemical performances. This work highlights the value of investigating novel structures and offers a technique for the creation of NaFePO4@C-based cathodes.
引用
收藏
页数:12
相关论文
共 50 条
  • [21] Olivine NaFePO4 cathode synthesized by a green aqueous electrochemical conversion route for sodium ion batteries
    Fang, Yongjin
    Xiao, Lifen
    Ai, Xinping
    Yang, Hanxi
    Cao, Yuliang
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [22] Comparison of electrochemical performances of olivine NaFePO4 in sodium-ion batteries and olivine LiFePO4 in lithium-ion batteries
    Zhu, Yujie
    Xu, Yunhua
    Liu, Yihang
    Luo, Chao
    Wang, Chunsheng
    NANOSCALE, 2013, 5 (02) : 780 - 787
  • [23] Easy approach of highly electrochemical-active maricite NaFePO4 cathode for low cost and high rate sodium-ion batteries
    Lu, Xinhao
    Liu, Xiao
    Li, Yuanhang
    Wang, Congling
    Zhang, Peng
    Shi, Peng
    Xu, Shuyin
    Lyu, Yingchun
    Zhu, Chengjun
    APPLIED PHYSICS LETTERS, 2023, 123 (04)
  • [24] Achieving highly electrochemically active maricite NaFePO4 with ultrafine NaFePO4@C subunits for high rate and low temperature sodium-ion batteries
    Liu, Bingqiu
    Zhang, Qi
    Li, Lu
    Zhang, Lingyu
    Jin, Zhanshuang
    Wang, Chungang
    Su, Zhongmin
    CHEMICAL ENGINEERING JOURNAL, 2021, 405
  • [25] Sodium-Ion Battery based on an Electrochemically Converted NaFePO4 Cathode and Nanostructured Tin-Carbon Anode
    Hasa, Ivana
    Hassoun, Jusef
    Sun, Yang-Kook
    Scrosati, Bruno
    CHEMPHYSCHEM, 2014, 15 (10) : 2152 - 2155
  • [26] Heat generation rates of NaFePO4 electrodes for sodium-ion batteries and LiFePO4 electrodes for lithium-ion batteries: a comparative study
    C. Heubner
    M. Schneider
    A. Michaelis
    Journal of Solid State Electrochemistry, 2018, 22 : 1099 - 1108
  • [27] The research progress of cathode material for sodium-ion batteries
    Yang, Shaobin
    Dong, Wei
    Shen, Ding
    Wang, Xiaoliang
    Li, Sinan
    Wang, Feng
    Wang, Yang
    Sun, Wen
    Gongneng Cailiao/Journal of Functional Materials, 2015, 46 (13): : 13001 - 13006
  • [28] Heat generation rates of NaFePO4 electrodes for sodium-ion batteries and LiFePO4 electrodes for lithium-ion batteries: a comparative study
    Heubner, C.
    Schneider, M.
    Michaelis, A.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2018, 22 (04) : 1099 - 1108
  • [29] Sodium chromium hexacyanoferrate as a potential cathode material for aqueous sodium-ion batteries
    Baster, Dominika
    Oveisi, Emad
    Mettraux, Pierre
    Agrawal, Surbhi
    Girault, Hubert H.
    CHEMICAL COMMUNICATIONS, 2019, 55 (97) : 14633 - 14636
  • [30] Remarkable enhancement in the electrochemical activity of maricite NaFePO4 on high-surface-area carbon cloth for sodium-ion batteries
    Ma, Xudong
    Xia, Jiuyang
    Wu, Xuehang
    Pan, Zhiyi
    Shen, Pei Kang
    CARBON, 2019, 146 : 78 - 87