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Plasmon-enhanced hydrogen production from photocatalytic methanol aqueous-phase reforming over novel nickel-tin intermetallic compounds photocatalyst
被引:0
|作者:
Wang, Ruiyi
[1
]
Lv, Mingyue
[2
]
Zhang, Jin
[1
]
Wang, Fei
[3
]
Wang, Xiaoli
[3
]
Wang, Ning
[4
]
Yu, Guangtao
[2
]
Zheng, Zhanfeng
[1
]
机构:
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, POB 165, Taiyuan 030001, Peoples R China
[2] Fujian Normal Univ, Coll Chem & Mat Sci, Engn Res Ctr Ind Biocatalysis, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Peoples R China
[3] Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
[4] Beijing Univ Technol, Fac Environm & Life, Beijing 100124, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Hydrogen production;
NiSn intermetallic compounds;
Plasmons;
Hot carrier;
Photocatalysis;
DENSITY-FUNCTIONAL THEORY;
ETHYLENE-GLYCOL;
H-2;
PRODUCTION;
ACETIC-ACID;
CATALYST;
ENERGY;
DEHYDROGENATION;
CONVERSION;
OXIDATION;
ELECTRON;
D O I:
10.1016/j.cej.2024.157981
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Hydrogen production from the aqueous phase reforming (APR) of methanol is promising to reduce the global carbon dioxide emission, but it is still a great challenge for hydrogen production with high catalytic efficiency at low reaction temperature. Here we report that Al2O3 supported Ni3Sn1 intermetallic compounds nanoparticles as new class of plasmonic photocatalyst and enables low temperature (150-190 degrees C), efficient hydrogen production (277 mu mol g-1 min-1 ) and low CO and CH4 selectivity (<= 0.1 %) through APR with the help of light irradiation. The hydrogen production rate of Ni3Sn1/Al2O3 is 8 times higher than that of conventional noble metal 3 wt% Pt/ Al2O3 catalyst under the same optimized reaction conditions. The exceptional photocatalytic performance for hydrogen production can be attribute to higher efficiency of "hot electron" transference into the reactant due to the higher energy level of "hot electron" and the lower energy level of metal-reactant adsorption bond induced by Sn doping in Ni3Sn1 under light irradiation, which not only improve the reactivity via enhanced methanol dissociation and the sequential water-gas shift (WGS) reaction, but also suppressed catalyst poisoning via accelerated CO2 desorption over the Ni sites.
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