Integrated electro- and chemical characterization of sulfide-based solid-state electrolytes

被引:2
|
作者
Li, Yuanshun [1 ,2 ]
Lehmann, Michelle [1 ]
Cheng, Lei [1 ]
Zawodzinski, Thomas A. [1 ,2 ]
Nanda, Jagjit [3 ]
Yang, Guang [1 ]
机构
[1] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA
[2] Univ Tennessee Knoxville, Dept Chem Engn, Knoxville, TN 37966 USA
[3] SLAC Natl Accelerator Lab, Appl Energy Div, 2575 Sand Hill Rd,Mailstop 0027, Menlo Pk, CA 94025 USA
来源
MATERIALS ADVANCES | 2024年 / 5卷 / 23期
关键词
LITHIUM; ION; BATTERIES; PERFORMANCE; CONDUCTIVITY; PRINCIPLES; INTERFACE; CATHODE; ANODES; EIS;
D O I
10.1039/d4ma00619d
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sulfide solid-state electrolytes (SSEs) represent a critical advancement towards enabling next-generation lithium metal batteries. However, a profound knowledge gap remains in understanding the structure-property relationships inherent to these sulfide SSEs. Electrochemical assessment and spectroscopic tools, such as Raman spectroscopy, offer bench-top ready, non-invasive, powerful avenues for operando and in situ analyses. Despite this potential, the integration of these methodologies, particularly for real-time interrogation, is markedly under-investigated. This review endeavors to catalog the use of diverse electrochemical techniques and spectroscopic tools in elucidating the structural and functional nuances of sulfide SSEs. Through the harmonization of these multifaceted evaluation strategies, our objective is to chart a course towards optimized sulfide SSEs, thereby aiding in the development of informed protocols for a deeper comprehension and understanding of the structure-property relationship and interfacial engineered design of solid-state batteries using sulfide-based SSEs. This review elaborates on the electrochemical characterization methods essential for the advancement sulfide-based solid-state electrolytes for lithium metal batteries, with a focus on the integration of spectroscopic tools like Raman spectroscopy.
引用
收藏
页码:9138 / 9159
页数:23
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