Nearly real trajectories in complex semiclassical dynamics
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作者:
Van Voorhis, Troy
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Dept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United StatesDept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United States
Van Voorhis, Troy
[1
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Heller, Eric J.
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Dept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United StatesDept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United States
Heller, Eric J.
[1
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机构:
[1] Dept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United States
The possibility that the dominant contributions by themselves may give a faithful representation of the true result was examined. As such, calculations of the auto-correlation function of the quartic anharmonic oscillator and the photodissociation of CO2, which show that including only the nearly real trajectories can give excellent results for realistic potentials were given. The use of only nearly real paths was particularly appealing because it allows one to overcome both of the major obstacles that have heretofore limited complex semiclassical approaches.
机构:
Univ Autonoma Chihuahua, Fac Ingn, Nuevo Campus Univ, Chihuahua 31125, MexicoUniv Autonoma Chihuahua, Fac Ingn, Nuevo Campus Univ, Chihuahua 31125, Mexico
Hernandez, Hector H. Hernandez
Valdez, Carlos R. Javier
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Univ Autonoma Chihuahua, Fac Ingn, Nuevo Campus Univ, Chihuahua 31125, MexicoUniv Autonoma Chihuahua, Fac Ingn, Nuevo Campus Univ, Chihuahua 31125, Mexico
机构:
Division of Mathematics and Mathematical Science, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso
College of Mathematics, Inner Mongolia University for the Nationalities, Tongliao, Inner Mongolia Autonomous 028043Division of Mathematics and Mathematical Science, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso
Bao T.
Adachi T.
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Department of Mathematics, Nagoya Institute of Technology, GokisoDivision of Mathematics and Mathematical Science, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso