Nearly real trajectories in complex semiclassical dynamics

被引:0
|
作者
Van Voorhis, Troy [1 ]
Heller, Eric J. [1 ]
机构
[1] Dept. of Chem. and Chemical Biology, Department of Physics, Harvard University, Cambridge, MA 02138, United States
关键词
Autocorrelation function - Photodissociation spectrum - Quantum dynamics - Quantum propagator - Quartic anharmonic oscillator - Semiclassical propagator;
D O I
暂无
中图分类号
学科分类号
摘要
The possibility that the dominant contributions by themselves may give a faithful representation of the true result was examined. As such, calculations of the auto-correlation function of the quartic anharmonic oscillator and the photodissociation of CO2, which show that including only the nearly real trajectories can give excellent results for realistic potentials were given. The use of only nearly real paths was particularly appealing because it allows one to overcome both of the major obstacles that have heretofore limited complex semiclassical approaches.
引用
收藏
页码:1 / 050501
相关论文
共 50 条
  • [41] Some new classical and semiclassical models for describing tunneling processes with real-valued classical trajectories
    Xing, JH
    Coronado, EA
    Miller, WH
    JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (28): : 6574 - 6578
  • [42] Semiclassical trajectories in the double-slit experiment
    Hernandez, Hector H. Hernandez
    Valdez, Carlos R. Javier
    PHYSICA SCRIPTA, 2023, 98 (02)
  • [43] Semiclassical Resonances Generated by Crossings of Classical Trajectories
    Higuchi, Kenta
    COMPTES RENDUS MATHEMATIQUE, 2021, 359 (06) : 657 - 663
  • [44] Circular trajectories on real hypersurfaces in a nonflat complex space form
    Bao T.
    Adachi T.
    Journal of Geometry, 2009, 96 (1-2) : 41 - 55
  • [45] Fundamental Dynamics of Popularity-Similarity Trajectories in Real Networks
    Papaefthymiou, Evangelos S.
    Iordanou, Costas
    Papadopoulos, Fragkiskos
    PHYSICAL REVIEW LETTERS, 2024, 132 (25)
  • [46] Spin effects on the semiclassical trajectories of Dirac electrons
    Gutierrez-Jauregui, R.
    Perez-Pascual, R.
    Jauregui, R.
    PHYSICAL REVIEW A, 2017, 96 (05)
  • [47] Universality of Regge and vibrational trajectories in a semiclassical model
    Silvestre-Brac, B
    Brau, F
    Semay, C
    PHYSICAL REVIEW D, 1999, 59 (01)
  • [48] NEW SEMICLASSICAL APPROXIMATION FOR QUARKONIA REGGE TRAJECTORIES
    KOBYLINSKY, NA
    STEPANOV, SS
    TUTIK, RS
    PHYSICS LETTERS B, 1990, 235 (1-2) : 182 - 186
  • [49] Coherent states expectation values as semiclassical trajectories
    Dias, N. C.
    Mikovic, A.
    Prata, J. N.
    JOURNAL OF MATHEMATICAL PHYSICS, 2006, 47 (08)
  • [50] DYNAMICS BY SEMICLASSICAL METHODS
    HERMAN, MF
    ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1994, 45 : 83 - 111