Solubility of carbon dioxide in three [Tf2N] ionic liquids

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作者
Tagiuri, Ali [1 ]
Sumon, Kazi Z. [1 ]
Henni, Amr [1 ]
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[1] Industrial Systems Engineering Faculty of Engineering and Applied Science, University of Regina, Regina,SK, Canada
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Equations of state - Ionic liquids - Carbon dioxide;
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摘要
The solubility of carbon dioxide in three bis(trifluoromethylsulfonyl)imide-based ionic liquids: N-methyl-n-pentylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([p(5)mpyrr][Tf2N]), 1-butyl-2,3-dimethylimidazolium bis(trifluoromethyl sulfonyl)imide ([bmmim][Tf2N]), and tributylmethylphosphonium bis(trifluoromethyl sulfonyl)imide ([P4441][Tf2N]) was measured at 298.15, 313.15, and 343.15K and pressures up to about 1.9MPa. The data were well correlated with the Soave-Redlich-Kwong equation of state (SRK-EoS). Henry's law constants for CO2 in the three ILs ([p(5)mpyrr][Tf2N], [bmmim][Tf2N], and [P4441][Tf2N]) at 298.15K were 3.1, 3.5, and 3.3MPa, respectively. © 2014 Elsevier B.V..
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页码:39 / 47
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