Undirected dehydrogenative silylation of aromatic C-H bond

被引:0
|
作者
Yurino T.
机构
来源
Yurino, Taiga (tyurino@eng.hokudai.ac.jp) | 1600年 / Society of Synthetic Organic Chemistry卷 / 75期
关键词
Attractive strategies - Biaryls - C-H bond - Cost efficiency - Coupling reaction - Environmental friendliness - Silylations;
D O I
10.5059/yukigoseikyokaishi.75.64
中图分类号
学科分类号
摘要
Arylsilanes are valuable intermediates for synthesis of various compounds, such as biaryls, by simple transformations. For synthesis of arylsilanes, direct C-H/Si-H coupling reaction is an attractive strategy from the both viewpoints of cost efficiency and environmental friendliness. This review described recent achievement of intermolecular dehydrogenative C-H silylation of undirected aromatic compounds.
引用
收藏
页码:64 / 65
页数:1
相关论文
共 50 条
  • [41] Silylation of C-H bonds in aromatic heterocycles by an Earth-abundant metal catalyst
    Toutov, Anton A.
    Liu, Wen-Bo
    Betz, Kerry N.
    Fedorov, Alexey
    Stoltz, Brian M.
    Grubbs, Robert H.
    NATURE, 2015, 518 (7537) : 80 - 84
  • [42] Regioselective β-silylation of porphyrins via iridium-catalyzed C-H bond activation
    Sugita, Noriaki
    Hayashi, Satoshi
    Shibata, Masashi
    Endo, Taiga
    Noji, Masahiro
    Takatori, Kazuhiko
    Takanami, Toshikatsu
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2016, 14 (43) : 10189 - 10192
  • [43] Pd-catalyzed silylation of alkenes via allylic C-H bond functionalization
    Zhao, Tony S. N.
    Larsson, Johanna M.
    Szabo, Kalman J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [44] Fast and Selective Dehydrogenative C-H/C-H Arylation Using Niechanochemistry
    Lou, Shao-Jie
    Mao, Yang-Jie
    Xu, Dan-Qian
    He, Jiang-Qi
    Chen, Qi
    Xu, Zhen-Yuan
    ACS CATALYSIS, 2016, 6 (06): : 3890 - 3894
  • [45] Cross Dehydrogenative Arylation (CDA) of a Benzylic C-H Bond with Arenes by Iron Catalysis
    Li, Yi-Zhou
    Li, Bi-Jie
    Lu, Xing-Yu
    Lin, Song
    Shi, Zhang-Jie
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (21) : 3817 - 3820
  • [46] Synthesis and Properties of Sila[n]helicenes via Dehydrogenative Silylation of C-H Bonds under Rhodium Catalysis
    Murai, Masahito
    Okada, Ryo
    Nishiyama, Atsushi
    Takai, Kazuhiko
    ORGANIC LETTERS, 2016, 18 (17) : 4380 - 4383
  • [47] Catalytic Silylation of Unactivated C-H Bonds
    Cheng, Chen
    Hartwig, John F.
    CHEMICAL REVIEWS, 2015, 115 (17) : 8946 - 8975
  • [48] Palladium-Catalyzed Remote meta-Selective C-H Bond Silylation and Germanylation
    Modak, Atanu
    Patra, Tuhin
    Chowdhury, Rajdip
    Raul, Suman
    Maiti, Debabrata
    ORGANOMETALLICS, 2017, 36 (13) : 2418 - 2423
  • [49] Improvements of efficiency and regioselectivity in the iridium(I)-catalyzed aromatic C-H silylation of arenes with fluorodisilanes
    Saiki, Takeaki
    Nishio, Yukihiro
    Ishiyama, Tatsuo
    Miyaura, Norio
    ORGANOMETALLICS, 2006, 25 (26) : 6068 - 6073
  • [50] A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds
    Su, Bo
    Zhou, Tai-Gang
    Li, Xian-Wei
    Shao, Xiao-Ru
    Xu, Pei-Lin
    Wu, Wen-Lian
    Hartwig, John F.
    Shi, Zhang-Jie
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (04) : 1092 - 1096