Inadvertent production and explosion of liquid chlorine dioxide

被引:0
|
作者
Sattelberger, Alfred P. [1 ]
Robinson, Jeanne M. [1 ]
Currier, Robert P. [1 ]
机构
[1] Los Alamos National Laboratory, Los Alamos, NM, United States
来源
Chemical and Engineering News | 2002年 / 80卷 / 49期
关键词
Gas-phase decomposition;
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摘要
A report on the inadvertent production and explosion of liquid chlorine dioxide is presented. The concentration of chlorine dioxide in the reactor effluent was limited by stoichiometry to twice the concentration in the inlet feed gas. It was observed that higher concentrations can be handled safely, provided the temperature were kept below 300 K and the risk of photolytic decomposition was minimized.
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页码:4 / 5
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