Formation of Ni(Al,Mo) solid solutions by mechanical alloying and their ordering on heating

被引:0
|
作者
Portnoj, V.K. [1 ]
Blinov, A.M. [1 ]
Tomilin, I.A. [1 ]
Kulik, T. [1 ]
机构
[1] MGU im. M.V. Lomonosova, Moscow, Russia
来源
Metally | 2002年 / 04期
关键词
Aluminum - Composition effects - Mechanical alloying - Molybdenum - Nickel - Order disorder transitions - Phase composition - Solid solutions;
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摘要
Solid solutions are formed as a result of mechanical alloying the powder mixtures of two compositions, namely, Ni70Al25Mo5 (I) and Ni75Al20Mo5 (II). The quantitative x-ray diffraction analysis showed that the atoms of Mo substitute completely the positions of Al in I mixture after mechanical alloying with formation of ternary ordered phase [Ni75(Al,Mo)25]. In this case, such distribution holds after heating up to 700°C. A metastable solid solution of Ni(Al,Mo) is formed in II mixture, that decomposes under heating with precipitation of Mo particles and L12-type ordering the retained aluminide.
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页码:105 / 109
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