Research progress on modification of magnetic chitosan microspheres and its application in water treatment

被引:0
|
作者
Feng Y. [1 ]
Cui Q. [1 ]
Xie Y. [1 ]
Zhao M. [1 ]
Zhang J. [1 ]
Dong X. [1 ]
机构
[1] School of Mechanical and Power Engineering, Shenyang University of Chemical Technology, Shenyang
关键词
Adsorbents; Chitosan microspheres; Heavy metals; Magnetic nanoparticles; Modification method; Wastewater;
D O I
10.13801/j.cnki.fhclxb.20211105.003
中图分类号
学科分类号
摘要
Magnetic chitosan microsphere (MCM) is a new type of adsorption material, which has unique magnetic response characteristics and good adsorption performance. With its outstanding environmental protection and controllability, it has attracted high attention in many fields such as biomedicine, food engineering, sewage treatment and so on. MCM prepared by traditional methods has some problems, such as nanoparticles are easy to dissolve in acidic solution and narrow application range. Therefore, researchers have carried out a lot of work in its optimization and modification. In this paper, the research progress of optimizing MCM was reviewed in detail from two aspects: magnetic nanoparticles modification and chitosan modification, including modification and replacement of magnetic nanoparticles, chitosan molecular imprinting modification, grafting modification, metal chelation modification, alkylation modification and so on. The adsorption and removal effects of modified MCM on heavy metal ions in wastewater and ionic dyes in printing and dyeing waste were summarized. Finally, the problems and challenges faced by modified MCM were discussed. Its future development trend was prospected, and the methods and ideas to further improve the application efficiency of modified MCM were put forward. Copyright ©2022 Acta Materiae Compositae Sinica. All rights reserved.
引用
收藏
页码:2543 / 2555
页数:12
相关论文
共 71 条
  • [11] CAI Y, ZHENG L, FANG Z., Selective adsorption of Cu(II) from an aqueous solution by ion imprinted magnetic chitosan microspheres prepared from steel pickling waste liquor, RSC Advances, 5, 118, pp. 97435-97445, (2015)
  • [12] LI X, ZENG D, Ping K, Et al., Synthesis and characterization of magnetic chitosan microspheres for drug delivery, RSC Advances, 10, 12, pp. 7163-7169, (2020)
  • [13] YANG H, YUAN B, LU Y, Et al., Preparation of magnetic chitosan microspheres and its applications in wastewater treatment, Science in China, 52, 3, pp. 249-256, (2009)
  • [14] ATANGANA E, CHIWESHE T T., Metal adsorbance in abattoir wastewater using cross-linked chitosan derivatives, Journal of Polymers and the Environment, 27, 11, pp. 2624-2636, (2019)
  • [15] LUCIA P, OLGA R, GALAMBOSl, Et al., Sorption of technetium on glutaraldehyde crosslinked chitosan, Journal of Radioanalytical & Nuclear Chemistry, 309, 3, pp. 1251-1256, (2016)
  • [16] JULIA M, FRICK P, NICOLE Z, Et al., Impact of acid type and glutaraldehyde crosslinking in the physicochemical and mechanical properties and biodegradability of chitosan films, Polymer Bulletin, 78, 2, pp. 981-1000, (2020)
  • [17] AKIN D, YAKAR A, GNDZ U., Synthesis of magnetic Fe<sub>3</sub>O<sub>4</sub>-chitosan nanoparticles by ionic gelation and their dye removal ability, Water Environment Research, 87, 5, pp. 425-436, (2015)
  • [18] GIRALDO J D, CAMPOS-REQUENA V H, RIVAS B L., Chitosan-tripolyphosphate bead: The interactions that govern its formation, Polymer Bulletin, 76, 8, pp. 3879-3903, (2018)
  • [19] BHUMKAR D R, POKHARKAR V B., Studies on effect of pH on cross-linking of chitosan with sodium tripolyphosphate: A technical note, Aaps Pharmscitech, 7, 2, pp. 138-143, (2006)
  • [20] YANG Qing, LIANG Borun, DOU Fengdong, Et al., exploration on cross-linking mechanism of chitosan fiber with glyoxal as cross-linking reagent, Journal of Cellulose Science and Technology, 4, pp. 13-20, (2005)