Selective synthesis of cyclic compounds by palladium-catalyzed cyclization of propargylic esters with nucleophiles

被引：0
|
作者：
Yoshida M. [1 ]
机构：
[1] Faculty of Pharmaceutical Sciences, Tokushima Bunri University, 180 Yamashiro-cho, Tokushima
来源：
Yoshida, Masahiro (yoshida@ph.bunri-u.ac.jp) | 1600年 / Society of Synthetic Organic Chemistry卷 / 75期
基金：
日本学术振兴会;
关键词：
Cascade reaction; Cyclic molecules; Cyclization; Diastereoselective reaction; Nucleophiles; Oxazolidinone; Palladium; Propargylic compounds; Regioselective reaction;
D O I：
10.5059/yukigoseikyokaishi.75.38
中图分类号：
学科分类号：
摘要：
Palladium-catalyzed cyclization of propargylic esters with bis-nucleophiles is one of the useful method for the construction of cyclic molecules in one step. A variety of products could be synthesized in one step by the choice of adequately designed nucleophilic molecules. In this review, we describe a comprehensive overview of our studies on palladium-catalyzed reactions of propargylic esters with bis-nucleophiles. The reactions afforded various functionalized hetero- and carbocyclic molecules in a regio- and stereoselective manner.
引用
收藏
页码：38 / 48
页数：10
相关论文
共 50 条
  • [41] A PALLADIUM-CATALYZED SYNTHESIS OF BENZYL ESTERS FROM METHYLBENZENES
    BRYANT, DR
    MCKEON, JE
    REAM, BC
    JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (11): : 4123 - &
  • [42] Palladium-Catalyzed Para-Selective Difluoromethylation of Arene Esters
    Tu, Guangliang
    Wang, Dongjie
    Yuan, Chunchen
    Zhang, Jingyu
    Zhao, Yingsheng
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (16): : 10740 - 10749
  • [43] Palladium-catalyzed α-arylation of esters
    Buchwald, S.L., 1600, American Chemical Society (123):
  • [44] Selective Palladium-Catalyzed α,β-Homodiarylation of Vinyl Esters in Aqueous Medium
    Trzepizur, Damian
    Brodzka, Anna
    Koszelewski, Dominik
    Wilk, Monika
    Ostaszewski, Ryszard
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (44) : 6028 - 6036
  • [45] Palladium-catalyzed α-arylation of esters
    Moradi, WA
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) : 7996 - 8002
  • [46] Palladium-Catalyzed α-Arylation of Cyclic Vinylogous Esters for the Synthesis of γ-Arylcyclohexenones and Total Synthesis of Aromatic Podocarpane Diterpenoids
    Hou, Wen-Yi
    Wu, Yen-Ku
    ORGANIC LETTERS, 2017, 19 (05) : 1220 - 1223
  • [47] Synthesis of coumestans by selective electrophilic cyclization followed by palladium-catalyzed intramolecular carbonylation: An efficient synthesis of coumestrol
    Yue, DW
    Larock, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U117 - U117
  • [48] NICKEL-CATALYZED AND PALLADIUM-CATALYZED ADDITIONS OF NUCLEOPHILES TO CYCLIC 1,3-DIENES
    ANDELL, OS
    BACKVALL, JE
    MOBERG, C
    ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1986, 40 (03): : 184 - 189
  • [49] Palladium-catalyzed heteroannulation of catechol with functionalized propargylic carbonates: Influence of the functional group on the regioselectivity of the cyclization
    Dominczak, Norbert
    Lhoste, Paul
    Kryczka, Boguslaw
    Sinou, Denis
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 264 (1-2) : 110 - 118
  • [50] Palladium-Catalyzed Coupling of Propargylic Carbonates with N-Tosylhydrazones: Highly Selective Synthesis of Substituted Propargylic N-Sulfonylhydrazones and Vinylallenes
    Chen, Zi-Sheng
    Duan, Xin-Hua
    Wu, Lu-Yong
    Ali, Shaukat
    Ji, Ke-Gong
    Zhou, Ping-Xin
    Liu, Xue-Yuan
    Liang, Yong-Min
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (25) : 6918 - 6921
12345