Synthesis of biodegradable superabsorbent hydrogels with using agricultural and horticultural

被引:0
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作者
Sadeghi, Mohammad [1 ]
Heidari, Behrouz [2 ]
Montazeri, Korush [1 ]
机构
[1] Department of Chemistry, Science Faculty, Islamic Azad University, Arak Branch, Arak, Iran
[2] Department of Chemical Engineering, Engineer Faculty, Islamic Azad University, Arak Branch, Arak, Iran
关键词
Potassium compounds - Grafting (chemical) - Hydrogels - Carboxylic acids - Free radicals - Scanning electron microscopy - Swelling;
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摘要
In this research we synthesized graft copolymerization of acrylic acid with pectin by using potassium persulfate (KPS) as a free radical initiator and agent methylen bisacrylamid (MBA) as a cross linker.The polymer structures were confirmed by scanning electron microscopy (SEM). Also we suggested a mechanism for copolymerization of acrylic acid with pectin. The effecting onto copolymerization parameters were systematically optimized to achieve a hydrogel with swelling capacity as high as possible. Maximum water absorbency of the optimized final product was found to be 590 gr/gr. the swelling capacity of the synthesized hydrogels was also measured in various salt solutions. Farthermore, the swelling of superabsorbant hydrogel was measured in various Solutions with PH values ranging from 1 to 12. the hydrogels exhibited the highest swelling at PH 6 and 9. also the swelling kinetics in distilled water investigated.
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页码:404 / 405
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