Direct hydrogenation of nitroarenes and one-pot amidation using formic acid over heterogeneous palladium catalysts

被引：0

作者：

Li, Ze-Long ^{[1
,2
]}

Liu, Jian-Hua ^{[1
]}

Li, Jin-Lei ^{[1
,2
]}

Xia, Chun-Gu ^{[1
]}

Li, Fu-Wei ^{[1
]}

机构：

[1] State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

[2] University of the Chinese Academy of Sciences, Beijing 100049, China

来源：

Journal of Molecular Catalysis | 2013年 / 27卷 / 05期

关键词：

Amidation - Aromatic nitro compounds - Benzimidazole derivatives - Chemoselective reduction - Nitroarenes - Palladium catalyst - Pd catalyst - Pd/C catalyst;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A highly chemoselective reduction of a wide diversity of aromatic nitro compounds to the corresponding amines have been achieved by a combination of Pd catalysts and HCOOH in ethanol under mild conditions. Moreover, a direct route to formanilides and benzimidazole derivatives from aromatic nitro compound bearing different functional groups has been established by using Pd/C catalyst and HCOOH.

引用

页码：393 / 399

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