Synthesis of novel mercaptophenyl carbocyclic C-nucleoside analogue using sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis

被引：0

作者：

Li, Hua ^{[1
]}

Joon, Hee Hong ^{[1
]}

机构：

[1] BK-21 Project Team, College of Pharmacy, Chosun University, Gwangju 501-759, Korea, Republic of

来源：

Bulletin of the Korean Chemical Society | 2008年 / 29卷 / 04期

关键词：

Alkylation; -; Glycosylation; Phenols; Synthesis; (chemical);

D O I：

10.5012/bkcs.2008.29.4.847

中图分类号：

学科分类号：

摘要：

Novel mercaptophenyl carbocyclic C-nucleoside analogue was synthesized via a cyclopentenol intermediate 10, which was prepared using a sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM). Friedel-Crafts alkylation was then used to couple the thiophenol.

引用

页码：847 / 850

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