Polymerization of propylene with 1-alkenes using metallocene catalysts

被引：0
|
作者：
Van Reenen, Albert J. [1 ]
Brull, Robert [1 ]
Wahner, Udo [1 ]
Pasch, Harald [2 ]
机构：
[1] Department of Chemistry, University of Stellenbosch, P/Bag X1, Matieland 7602, South Africa
[2] Deutches Kunstoff Institut, Schlossgartenstrasse 6, 64289 Darmstadt, Germany
来源：
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry | 2000年 / 41卷 / 01期
关键词：
Catalysts - Copolymerization - Copolymers - Crystallization - Gel permeation chromatography - Molecular weight - Monomers - Nuclear magnetic resonance spectroscopy - Synthesis (chemical) - Thermoanalysis - X ray diffraction analysis;
D O I：
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中图分类号：
学科分类号：
摘要：
The copolymerization of propylene with 1-octene, 1-decene, 1-tetradecene, and 1-octadecene is investigated. The copolymers synthesized are characterized by NMR spectroscopy, thermal analysis, X ray diffraction (XRD), gel permeation chromatography (GPC) and crystallization analysis fractionation (CRYSTAF). This is done to correlate the effect of comonomer incorporation with crystallinity, crystallization temperature, melting point and molecular weight.
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页码：496 / 497
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