Visible light-promoted difluoromethylthiolation of aryldiazonium salts

被引：0
|
作者：
Wang W. [1 ,2 ]
Zhang S. [1 ,2 ]
Zhao H. [1 ,3 ]
Wang S. [1 ,2 ]
机构：
[1] School of Chemistry and Chemical Engineering, University of Jinan, 336 West Road of Nan Xinzhuang, Jinan
[2] Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical materials, 336 West Road of Nan Xinzhuang, Jinan
[3] Key Laboratory of Interfacial Reaction and Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, 336 West Road of Nan Xinzhuang Jinan, Shandong
来源：
Wang, Wengui (chm_wangwg@ujn.edu.cn) | 2018年 / Royal Society of Chemistry卷 / 16期
关键词：
Compendex;
D O I：
10.1039/C8OB02431F
中图分类号：
学科分类号：
摘要：
Difluoromethylthiolation of aryldiazonium salts under photocatalytic conditions with a shelf-stable, easily prepared and inexpensive reagent, PhSO 2 SCF 2 H was described. A variety of difluoromethylthioethers were obtained utilizing aryldiazonium salts containing different functional groups. Aryldiazonium salts with a heteroarene moiety were tolerated. Fluorescence quenching experiments indicated that both oxidative and reductive quenching cycles occurred during this process. © The Royal Society of Chemistry.
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页码：8565 / 8568
页数：3
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