Synthesis of poly(phenylene oxides) using horse-radish peroxidase

被引：0
|
作者：
Vlasov, G.P. [1 ]
Pankova, G.A. [1 ]
Il'ina, I.E. [1 ]
Vlasova, E.N. [1 ]
Volchek, B.Z. [1 ]
Bribanov, A.V. [1 ]
Gojkhman, M.I. [1 ]
机构：
[1] Inst. of Macromolecular Compounds, RAS, Bol'shoj pr. 31, Sankt-Peterburg, 199004, Russia
来源：
Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya | 2002年 / 44卷 / 05期
关键词：
Biosynthesis - Carboxylic acids - Conformations - Enzymes - Molecular weight distribution;
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学科分类号：
摘要：
The enzymatic synthesis of poly(phenylene oxides) from vanillic acid using horse-radish peroxidase was elaborated. It was shown that varying the conditions of synthesis makes it possible to control the polymer structure and its molecular mass distribution. The resulting polymers are branched (a soluble fraction) and strongly branched (an insoluble fraction) poly(phenylene oxides).
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页码：743 / 749
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