Isothermal crystallization behavior of biodegradable poly (butylene succinate-co-terephthalate) (PBST) copolyesters at high undercoolings

被引：0
|
作者：
Xu, Xin-Jian [1 ]
Li, Fa-Xue [1 ]
Luo, Sheng-Li [1 ]
Yu, Jian-Yong [1 ]
机构：
[1] College of Textiles, Donghua University, Shanghai 201620, China
来源：
Journal of Donghua University (English Edition) | 2008年 / 25卷 / 04期
关键词：
Undercooling - Nucleation - Butenes - Crystallization kinetics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Poly ( butylene succinate-co-terephthalate) (PBST) copolyesters were prepared by polycondensatioa The isothermal crystallization behavior of the as-prepared copolyesters was investigated by depolarized light intensity ( DLI ) at high undercoolings. According to Avrami equation, the exponent n, independent of the crystallization temperature, is at a range of 2.5 to 3. 4, which probably corresponds to the heterogeneous nucleation and a 3-dirnensional spherulitic growth. The maximum crystallization rate, very useful to polymer processing, was found at about 90°C based on the half-crystallization time t1/2analysis.
引用
收藏
页码：405 / 407
相关论文
共 50 条
  • [41] Sequence distribution and crystallization behavior on block copolyesters of poly(butylene glutarate-co-adipate-co-succinate) ternary random copolyester and poly(butylene terephthalate)
    Park, SS
    Kang, HJ
    POLYMER JOURNAL, 1999, 31 (03) : 238 - 245
  • [42] Miscibility and Crystallization Behaviors of Biodegradable Poly(butylene succinate-co-butylene terephthalate)/Phenoxy Blends
    Li, Zhisheng
    Yang, Fang
    Qiu, Zhaobin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 121 (02) : 720 - 726
  • [43] Crystallization, structures and properties of biodegradable poly (butylene succinate-co-butylene terephthalate) with a symmetric composition
    Zheng, Cui
    Zhu, Guixiang
    Shi, Ying
    Liu, Li-Zhi
    Ren, Minqiao
    Zhang, Wei
    Han, Ling
    MATERIALS CHEMISTRY AND PHYSICS, 2021, 260
  • [44] Studies on sequential structure of the biodegradable poly(butylene succinate-co-butylene terephthate) (PBST)
    Li, FX
    Zhang, HY
    Yu, JY
    PROCEEDINGS OF 2005 INTERNATIONAL CONFERENCE ON ADVANCED FIBERS AND POLYMER MATERIALS (ICAFPM 2005), VOL 1 AND 2: NEW CENTURY , NEW MATERIALS AND NEW LIFE, 2005, : 987 - 990
  • [45] Biodegradable Poly(butylene succinate-co-terephthalate) Fibers Incorporated with Nanoparticles under High Drawing Temperatures for Enhanced Mechanical Properties
    Gu, Jiayi
    Wei, Xing
    Hou, Xueni
    Wei, Zhenzhen
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2019, 304 (08)
  • [46] Synchronous Stimuli of Biodegradable Poly(butylene succinate-co-terephthalate) Copolymer Via Uniaxial Stretching at Varying Temperatures
    Wei, Zhenzhen
    Lin, Jinyou
    Tian, Feng
    Li, Faxue
    Yu, Jianyong
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2015, 53 (09) : 640 - 649
  • [47] Investigation on the gelation behavior of biodegradable poly(butylene succinate) during isothermal crystallization process
    Fa-liang Luo
    Xiu-qin Zhang
    Wei Ning
    Du-jin Wang
    Chinese Journal of Polymer Science, 2011, 29 : 251 - 258
  • [48] INVESTIGATION ON THE GELATION BEHAVIOR OF BIODEGRADABLE POLY(BUTYLENE SUCCINATE) DURING ISOTHERMAL CRYSTALLIZATION PROCESS
    Luo, Fa-liang
    Zhang, Xiu-qin
    Ning, Wei
    Wang, Du-jin
    CHINESE JOURNAL OF POLYMER SCIENCE, 2011, 29 (02) : 251 - 258
  • [49] Study on tensile properties of biodegradable poly(butylene succinate-co-butylene terephthalate) (PBST) fibers after heat-setting
    Ma Yanli
    Li Faxue
    Yu Jianyong
    Qian Jingfang
    PROCEEDINGS OF 2009 INTERNATIONAL CONFERENCE ON ADVANCED FIBERS AND POLYMER MATERIALS, VOLS 1 AND 2, 2009, : 943 - 945
  • [50] STRUCTURES OF POLY(ETHYLENE/BUTYLENE TEREPHTHALATE) COPOLYESTERS UNDER ISOTHERMAL CRYSTALLIZATION CONDITIONS
    Tung, Chia-Hsing
    Shyr, Tien-Wei
    86TH TEXTILE INSTITUTE WORLD CONFERENCE, VOL 1, CONFERENCE PROCEEDINGS, 2008,
12345