Synthesis of micro-mesoporous HKUST-1 with templates

被引：0
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作者：
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China [1 ]
机构：
来源：
Gongneng Cailiao | / 11卷 / 11112-11117期
关键词：
Microporous materials - Mesoporous materials - Swelling;
D O I：
10.3969/j.issn.1001-9731.2015.11.024
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学科分类号：
摘要：
Micro-mesoporous HKUST-1 materials with microporous and mesoporous structure were synthesized using a triblock copolymer surfactant P123 as a template and decane and 1,3,5-tri-methybenzene (TMB) as swelling agents by a hydrothermal method. The samples were characterized by XRD, N2 adsorption-desorption, SEM and TEM. The effects of the template content and different kinds of swelling agents on the pore structure and crystal morphology of HKUST-1 were studied. The results showed that the TMB was a favored swelling agent that helps to increase the mesopore volume; the addition of template and swelling agent has resulted in HKUST-1 crystals with different morphologies, and some flaky crystals under suitable conditions. ©, 2015, Journal of Functional Materials. All right reserved.
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