Insight into the corrosion inhibition performance of Capsicum annuum L. leaf extract as corrosion inhibitor for copper in sulfuric acid medium

被引:8
|
作者
Hu, Ping [1 ]
Cheng, Pengliang [1 ]
Wu, Yundong [2 ]
Guo, Lei [2 ]
Alobaid, Abeer A. [3 ]
机构
[1] Tongren Ecol Environm Bur, Tongren 554300, Peoples R China
[2] Tongren Univ, Sch Mat & Chem Engn, Tongren 554300, Peoples R China
[3] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
关键词
Corrosion inhibitor; Copper; Sulfuric acid; Capsicum annuum L. leaf extract; Electrochemical test; AFM; 0.5 M H2SO4; MILD-STEEL; HYDROCHLORIC-ACID; ANTICORROSION NATURE; ADSORPTION; SODIUM; FRUITS; AGENTS; CU;
D O I
10.1016/j.jtice.2024.105558
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Background: Metal corrosion and protection have always been popular areas of research. Corrosion inhibitors are of great significance in metal corrosion protection. In this study, pure water extraction technical was utilized to acquire Capsicum annuum L. leaf extract (CALLE). The corrosion protection property of CALLE was revealed through a combination of theoretical and experimental using electrochemical methods, theoretical calculation and morphology analysis of surface. Methods: In this study, we used polarization curve method and electrochemical impedance spectroscopy test to evaluate the corrosion inhibition performance of CALLE. Electrochemical test reveals that CALLE has exhibit high protection ability about corrosion. The corrosion inhibition efficiency can grow about 94 % as the contain rises 500 mg/L. As the temperature rises, its resistance efficiency can still be stabilized above 90 %. The test analyses of SEM and AFM convincing demonstration that CALLE can efficiently inhibit occurring about the corrosion in H2SO4 for copper. Significant findings: It results reveal that the four effective components for CALLE can emerge excellent inhibition ability through theoretical analysis of theoretical calculation. The adsorption isotherm model shows that the active ingredient about CALLE was adsorbed correspond with the Langmuir adsorption isotherm model, and exist simultaneously physical and chemical adsorption. CALLE prepared by pure water extraction method can effectively reduce the cost of corrosion inhibitor.
引用
收藏
页数:13
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