Preparation and microwave absorption performance of hollow iron-based carbon fiber composites

被引：0

作者：

Ma Q. ^{[1
]}

Qiang R. ^{[1
]}

Shao Y. ^{[2
]}

Yang X. ^{[1
]}

Xue R. ^{[1
]}

Chen B. ^{[1
]}

机构：

[1] College of Textiles, Zhongyuan University of Technology, Zhengzhou

[2] Faculty of Engineering, Huanghe S&T University, Zhengzhou

来源：

Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2024年 / 41卷 / 02期

关键词：

National Natural Science Foundation of China (51902359); Science and Technology Guidance Project of Textile Industry Federation (2021044); General Program of Zhongyuan University of Technology (K2023MS009); Backbone Teacher Program (2020XQG02);

D O I：

10.13801/j.cnki.fhclxb.20230613.002

中图分类号：

学科分类号：

摘要：

In order to improve the increasingly serious electromagnetic pollution caused by the rapid development of communication and electronic devices, and solve the problems of complicated preparation methods and high energy consumption of magnetic carbon-based absorbing materials, this project proposes a new method for developing iron-based carbon fiber absorbing materials. Using hollow poplar catkin fibers as carriers, Fe3+ as the metal source, and wet chemical adsorption and high-temperature carbon thermal reduction methods, Fe-FexOy/C composite materials with excellent microwave absorption properties were obtained. The experimental results show that as the calcination temperature increases, different iron oxides (Fe/Fe3O4/FeO) are generated by combining the iron component with oxygen-containing groups in the Yangxu fibers, and the coercivity and saturation magnetization of the material are enhanced, and the ferromagnetic properties are obvious. Fe-FexOy/C-600 has the best absorption performance, and the effective absorption bandwidth can reach 8.4 GHz (7.2-15.6 GHz) when the thickness of the absorber is 3 mm. The excellent absorption performance of the composite material is attributed to the synergy of impedance matching and dielectric loss and magnetic loss, and the mutually carried fiber structure builds a suitable attenuation space for electromagnetic waves and quickly attenuates in the carbon fiber conductive network. The research will provide reference for the design and development of new iron based carbon fiber absorbing materials. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.

引用

页码：1058 / 1069

页数：11

共 47 条

[21] SULTAN S, TIWARI J N, JANG J H, Et al., Highly efficient oxygen reduction reaction activity of graphitic tube encapsulating nitrided CoxFey alloy[J], Advanced Energy Materials, 8, 25, (2018)
[22] ZHANG X A, YAN F, ZHANG S, Et al., Hollow N-doped carbon polyhedron containing CoNi alloy nanoparticles embedded within few-layer N-doped graphene as high-performance electromagnetic wave absorbing material[J], ACS Applied Materials & Interfaces, 10, 29, pp. 24920-24929, (2018)
[23] LIU M M, YANG X F, SHAO W, Et al., Superior microwave absorbing properties of O, S, N codoped carbon planar helixes via carbonization of polypyrrole spiral nanowires[J], Carbon, 174, pp. 625-637, (2021)
[24] DING D, WANG Y, LI X D, Et al., Rational design of core-shell Co@C microspheres for high-performance microwave absorption[J], Carbon, 111, pp. 722-732, (2017)
[25] HE N, LIU M M, QI J Y, Et al., Plasmon resonance strategy to enhance permittivity and microwave absorbing performance of Cu/C core-shell nanowires[J], Chemical Engineering Journal, 378, (2019)
[26] YANG H J, CAO M S, LI Y, Et al., Enhanced dielectric properties and excellent microwave absorption of SiC powders driven with NiO nanorings[J], Advanced Optical Materials, 2, 3, pp. 214-219, (2014)
[27] YANG X F, FAN B X, TANG X, Et al., Interface modulation of chiral PPy/Fe3O4 planar microhelixes to achieve electric/ magnetic-coupling and wide-band microwave absorption[J], Chemical Engineering Journal, 430, (2022)
[28] LIU M M, WU L W, FAN B X, Et al., Governing the Ni content and size of 2D layered C/Ni nanoparticle composites for enhanced electromagnetic wave absorption[J], Applied Surface Science, 571, (2022)
[29] LIU P J, YAO Z J, ZHOU J T, Et al., Small magnetic Co-doped NiZn ferrite/graphene nanocomposites and their dual-region microwave absorption performance[J], Journal of Materials Chemistry C, 4, 41, pp. 9738-9749, (2016)
[30] LI Z X, LI X H, ZONG Y, Et al., Solvothermal synthesis of nitrogen-doped graphene decorated by superparamagnetic Fe3O4 nanoparticles and their applications as enhanced synergistic microwave absorbers[J], Carbon, 115, pp. 493-502, (2017)

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