Ring expansion reactions of P 00000000 00000000 00000000 00000000 11111111 00000000 11111111 00000000 00000000 00000000 O-containing molecules

被引:0
|
作者
Yang Z. [1 ]
Tam J.K.F. [1 ]
Wootton J.M. [1 ]
Lynam J.M. [1 ]
Unsworth W.P. [1 ]
机构
[1] Department of Chemistry, University of York, Heslington, York
关键词
Compilation and indexing terms; Copyright 2025 Elsevier Inc;
D O I
10.1039/d3cc02087h
中图分类号
学科分类号
摘要
A series of ring expansion reactions of P O-containing molecules have been developed for the synthesis of medium-sized ring cyclic phosphonate esters and phosphonamidates. The reactivity trends initially appear to be counter-intuitive, compared with more well established ring expansion reactions of lactam derivatives, but are explained by considering the differences in heteroatom bonding to P and C respectively. © 2023 The Royal Society of Chemistry.
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页码:7927 / 7930
页数:3
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