Research progress on NH3-SCR mechanism of metal-supported zeolite catalysts

被引:0
|
作者
Zhang W.-B. [1 ]
Chen J.-L. [1 ]
Guo L. [1 ]
Zheng W. [1 ]
Wang G.-H. [1 ]
Zheng S.-K. [2 ]
Wu X.-Q. [1 ]
机构
[1] Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan
[2] Hubei Key Laboratory for Processing and Application of Catalytic Materials, School of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang
基金
中国国家自然科学基金;
关键词
NH[!sub]3[!/sub]-SCR; Reaction kinetics; Reaction mechanism; Zeolite;
D O I
10.1016/S1872-5813(21)60080-4
中图分类号
学科分类号
摘要
Metal-supported zeolite catalysts have been widely used in the NH3 selective catalytic reduction (NH3-SCR) reactions due to their wide temperature window and good hydrothermal stability. In this review, the research progress in the structural characteristics, catalytic performance and reaction mechanism of Cu- and Fe-based zeolite catalysts in NH3-SCR was summarized. In addition, the application of density functional theory (DFT) calculation in clarifying the reaction mechanism of NH3-SCR was introduced. Finally, the reaction kinetics and the apparent kinetic parameters of different metal-based zeolite catalysts in NH3-SCR were compared and discussed. We hope this review could provide new ideas for the study of NH3-SCR reaction mechanism over metal-supported zeolite catalysts. © 2021, Science Press. All right reserved.
引用
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页码:1294 / 1315
页数:21
相关论文
共 129 条
  • [21] GAO F, MEI D H, WANG Y L, SZANYI J, PEDEN C H F., Selective catalytic reduction over Cu/SSZ-13: Linking homo- and heterogeneous catalysis[J], J Am Chem Soc, 139, 13, pp. 4935-4942, (2017)
  • [22] GAO F, ZHENG Y, KUKKADAPU R K, WANG Y L, WALTER E D, SCHWENZER B, SZANYI J, PEDEN C H F., Iron loading effects in Fe/SSZ-13 NH<sub>3</sub>-SCR catalysts: Nature of the Fe ions and structure-function relationships[J], ACS Catal, 6, 5, pp. 2939-2954, (2016)
  • [23] CHEN J L, PENG G, ZHANG W B, ZHENG W, GUO L, WU X Q., Excellent performance of one-pot synthesized Fe-containing MCM-22 zeolites for the selective catalytic reduction of NO<sub>x</sub> with NH<sub>3</sub>, Catal Sci Technol, 10, 19, pp. 1-16, (2020)
  • [24] WANG H, XU R N, JIN Y, ZHANG R D., Zeolite structure effects on Cu active center, SCR performance and stability of Cu-zeolite catalysts, Catal Today, 327, 1, pp. 295-307, (2019)
  • [25] LONG S Y, PENG D J, YAN Z, PO S W, YAN S X., Selective catalytic reduction of NO<sub>x</sub> with NH<sub>3</sub>: opportunities and challenges of Cu-based small-pore zeolites[J], Natl Sci Rev, 17, 3, (2021)
  • [26] RESINI C, MONTANARI T, NAPPI L, BAGNASCO G, ROCCHINI G, BUSCA G, BREGANI F, NOTARO M, ROCCHINI G., Selective catalytic reduction of NO<sub>x</sub> by methane over Co-H-MFI and Co-H-FER zeolite catalysts: Characterisation and catalytic activity[J], J Catal, 214, 2, pp. 179-190, (2003)
  • [27] ANTONIO G, ISABELLA N, ENRICO T., Ammonia blocking of the "Fast SCR" reactivity over a commercial Fe-zeolite catalyst for diesel exhaust aftertreatment, J Catal, 265, 2, pp. 141-147, (2009)
  • [28] GROSSALE A, NOVA I, TRONCONI E, CHATTERJEE D, WEIBEL M., The chemistry of the NO/NO<sub>2</sub>-NH<sub>3</sub> "fast" SCR reaction over Fe-ZSM5 investigated by transient reaction analysis, J Catal, 256, 2, pp. 312-322, (2008)
  • [29] LONG R Q, YANG R T., Superior ion-exchanged ZSM-5 catalysts for selective catalytic oxidation of ammonia to nitrogen[J], Chem Commun, 17, 17, pp. 1651-1652, (2000)
  • [30] GAO F, WALTER E D, WASHTON N M, SZANYI J, PEDEN C H F., Synthesis and evaluation of Cu/SAPO-34 catalysts for NH<sub>3</sub>-SCR 2: Solid-state ion exchange and one-pot synthesis, Appl Catal B: Environ, 162, 1, pp. 501-514, (2015)