Effects of Reaction Conditions on the Formation of Furfural Compounds in Maillard Reaction System of Glucose-Glycine

被引:0
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作者
Li Y. [1 ,2 ]
机构
[1] State Key Laboratory of Dairy Biotechnology, Shanghai Engineering Research Center of Dairy Biotechnology, Dairy Research Institute, Bright Dairy and Food Co., Ltd., Shanghai
[2] Synergetic Innovation Center for Food Safety and Nutrition, Jiangnan University, Wuxi
关键词
formation kinetics; furfural compounds; glucose; glycine; Maillard reaction;
D O I
10.13386/j.issn1002-0306.2022090148
中图分类号
学科分类号
摘要
The Maillard reaction system of glucose and glycine was applied to study the formations of furfural compounds. The effects of glucose/glycine molar concentration ratio, initial pH, heating temperature and time on the formations of 5-hydroxymethylfurfural (HMF), 2-furfural (F) and 5-methyl-2-furfural (MF) were evaluated. The kinetic equations of HMF, F and MF were established and their apparent activation energies were also predicted. The results showed that: Glucose/glycine molar concentration ratio had great influence on the formations of furfural compounds. The formation of HMF continued to increase with the increase of ratio, and the formations of F and MF reached the maximum when the ratio was 1:1. The acidic pH conditions could promote the formation of HMF, while the neutral and alkaline pH conditions were conducive to the formation of F. The total amount of furfural compounds decreased rapidly with the increase of pH. The amounts of HMF, F, and MF in the glucose-glycine reaction system increased with the increase of heating temperature and time. The formations of HMF and F in glucose and glycine model followed first-order kinetics model at lower temperatures (HMF: 70~110 ℃; F: 70 ℃), while their formations were in accordance with zero-order kinetics model at higher temperatures (HMF: 130 ℃; F: 90~130 ℃). The formation of MF followed zero-order kinetics model at 90~130 ℃. The results would provide guidance on the production and control of HMF, F, and MF in the food thermal processing industry. © 2023 Science and Technology of Food Industry. All rights reserved.
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页码:85 / 92
页数:7
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共 43 条
  • [11] SUN Y, MIAO R X., Discussion on the progress of 5-hydroxymethyl furfural in beverages [J], Food Research and Development, 39, 13, (2018)
  • [12] LIU X Y, CHEN X L, LIN T, Et al., Effects of roasting degree on formation of 5-hydroxymethylfurfural contents in coffea Arabica[J], Journal of Chinese Institute of Food Science and Technology, 22, 1, pp. 324-331, (2022)
  • [13] PELETEIRO S, LOPES A M D C, GARROTE G, Et al., Manufacture of furfural in biphasic media made up of an ionic liquid and a co-solvent[J], Industrial Crops and Products, 77, pp. 163-166, (2015)
  • [14] PESAVENTO M, MERLI D, BIESUZ R, Et al., A MIP-based low-cost electrochemical sensor for 2-furaldehyde detection in beverages[J], Analytica Chimica Acta, 1142, 15, pp. 201-210, (2021)
  • [15] BOEKEL M A J S V., Effect of heating on Maillard reactions in milk[J], Food Chemistry, 62, 4, (1998)
  • [16] KWAK E J, LIM S I., The effect of sugar, amino acid, metal ion, and NaCl on model Maillard reaction under pH control[J], Amino Acids, 27, 1, (2004)
  • [17] SUN F D, KONG B H, HAN Q, Et al., Influence of different initial pH and heating time on characteristic of the porcine bone protein hydrolysate Maillard products[J], Science and Technology of Food Industry, 34, 22, (2013)
  • [18] ZHANG L, KONG Y, YANG X, Et al., Kinetics of 5-hydrox-ymethylfurfural formation in the sugar-amino acid model of Maillard reaction[J], Journal of the Science of Food and Agriculture, 99, 5, pp. 2340-2347, (2018)
  • [19] ZHOU Y, LI Y, YU A., The effects of reactants ratios, reaction temperatures and times on Maillard reaction products of the L-ascorbic acid/L-glutamic acid system[J], Food Science and Technology, 36, 2, (2016)
  • [20] ZHANG F M, TANG G Q, TIAN W, Et al., Research on the process of glutamic acid and glucose Maillard reaction system[J], Journal of Chinese Institute of Food Science and Technology, 19, 3, pp. 49-59, (2019)