Energy-efficient semi-continuous distillation of a ternary mixture using combined tracking-economic model predictive control

Distillation is an energy-intensive separation technique. Semicontinuous distillation has gained attention as a cost-effective alternative to conventional multi-column distillation of multi-component mixtures. However, the cyclic behavior of semicontinuous distillation poses operational challenges considering cost of energy and need for maintaining consistent product purity. The challenge is addressed in this work by proposing a dual- objective Model Predictive Controller (MPC) that handles both product purity and energy consumption through a combined tracking-economic objective function. The proposed MPC features Extended Kalman Filter for state estimation and the successive linearization technique for building the prediction model. The nonlinear plant model is implemented in OpenModelica, which is linked to Matlab for MPC implementation. The effectiveness of the proposed MPC is demonstrated on semicontinuous distillation of Benzene, Toluene, and o-Xylene. The dual-objective MPC is shown to yield an energy saving of 8% per feed processed compared with conventional tracking MPC, while also performing well under process disturbances. It is also shown that the feed processed during a certain time period is 8% higher in the dual-objective MPC than the tracking MPC. The considerable economic improvement is gained without degrading the product purities, indicating that dual-objective MPC is an effective approach to energy-efficient operation of semicontinuous distillation.