EFFICACY OF DEEP EUTECTIC SOLVENTS (DESs) FOR MITIGATING BIODETERIORATION IN CULTURAL HERITAGE: IN SITU EVALUATION

被引:0
|
作者
Strangis, Romina [1 ]
Macchia, Andrea [2 ,3 ]
Gabriele, Bartolo [1 ]
Mancuso, Raffaella [1 ]
LA Russa, Mauro Francesco [2 ]
机构
[1] Univ Calabria, Dept Chem & Chem Technol, Lab Ind & Synthet Organ Chem LISOC, Via Pietro Bucci 12-C, I-87036 Arcavacata Di Rende, Italy
[2] Univ Calabria, Dept Biol Ecol & Earth Sci DiBEST, Via Pietro Bucci, I-87036 Arcavacata Di Rende, CS, Italy
[3] YOuth Conservat Cultural Heritage, YOCOCU, Via T Tasso 108, I-00185 Rome, Italy
关键词
Deep Eutectic Solvents (DESs); Green solvent; Biocide; Cultural Heritage treatment; Stone material; QUATERNARY AMMONIUM-COMPOUNDS; ANTIBACTERIAL ACTIVITY; CONSERVATION; AGENTS; ZINC;
D O I
10.36868/IJCS.2024.03.01
中图分类号
J [艺术];
学科分类号
13 ; 1301 ;
摘要
The preservation of stone materials faces significant challenges due to biological deterioration, compromising the visual appearance and structural integrity of artifacts. Current cleaning treatments use toxic chemical biocides, with a high impact on the environment and human health. Research is turning to eco -friendly alternatives, such as Deep Eutectic Solvents (DESs), which offer a promising combination of biocidal properties and eco-friendly, as well as features such as biodegradability, non-flammability and nonvolatility. This study defines the efficacy of Choline Chloride-based DESs reported in the literature as biocides in a real case study on an outdoor exposed magmatic effusive rock at the University of Calabria. Several analytical techniques were used to define DESs biocidal efficacy, monitoring their action for 6 months. This study contributes to the evidence of DESs' ability to keep treated surfaces clean, thus promoting the long-term preservation of materials. Macroscopic and microscopic observations, spectrocolorimetry, bioluminometry and FTIR spectroscopy have highlighted the significant potential of DESs as sustainable biocidal solvents for the preservation of stone materials exposed outdoors.
引用
收藏
页码:1147 / 1164
页数:18
相关论文
共 50 条
  • [41] Adsorption behavior of Cr(VI) by biomass-based adsorbent functionalized with deep eutectic solvents (DESs)
    Qian Li
    Qing Huang
    Xin Ya Pan
    Hang Yu
    Zi Tong Zhao
    BMC Chemistry, 16
  • [42] Recovery of Cu from waste smelting slag through extraction with novel deep eutectic solvents (DESs)
    Mohammad, Nisar
    Faizan, Muhammad
    Zia, Zeeshan
    Ahmad, Iftikhar
    Awan, Muhammad Emmad Ul Hassan
    Roedar, Ayesha
    Ahmad, Waqas
    CANADIAN METALLURGICAL QUARTERLY, 2025, 64 (02) : 723 - 730
  • [43] Deep Eutectic Solvents (DESs)-Ultrasonic-Assisted Extraction of Paeoniflorin and Paeonol from Moutan Cortex
    Chen, Zhuo
    Zhang, Jinnan
    Yang, Fuwei
    JOURNAL OF CHEMISTRY, 2022, 2022
  • [44] 15α-hydroxylation of D-ethylgonendione by Penicillium raistrickii in deep eutectic solvents DESs containing system
    Mao, Shuhong
    Wang, Xiaorui
    Zhang, Zhaohui
    Wang, Shan
    Li, Kang
    Lu, Fuping
    Qin, Huimin
    BIOCHEMICAL ENGINEERING JOURNAL, 2020, 164 (164)
  • [45] Screening of deep eutectic solvents (DESs) as green CO2 sorbents: from solubility to viscosity
    Sarmad, Shokat
    Xie, Yujiao
    Mikkola, Jyri-Pekka
    Ji, Xiaoyan
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (01) : 290 - 301
  • [46] Deep eutectic solvents (DESs) as eco-friendly and sustainable solvent/catalyst systems in organic transformations
    Khandelwal, Sarita
    Tailor, Yogesh Kumar
    Kumar, Mahendra
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 215 : 345 - 386
  • [47] Comprehensive evaluation on tailor-made deep eutectic solvents (DESs) in extracting tea saponins from seed pomace of Camellia oleifera Abel
    Tang, Yayuan
    He, Xuemei
    Sun, Jian
    Liu, Guoming
    Li, Changbao
    Li, Li
    Sheng, Jinfeng
    Zhou, Zhugui
    Xin, Ming
    Ling, Dongning
    Yi, Ping
    Zheng, Fengjin
    Li, Jiemin
    Li, Zhichun
    Yang, Ying
    Tang, Jie
    Chen, Xi
    FOOD CHEMISTRY, 2021, 342
  • [48] An environmentally friendly method for extraction of cobalt and molybdenum from spent catalysts using deep eutectic solvents (DESs)
    Ebrahimi, Ehsan
    Safari, Hassan
    Rezaee, Mohammad
    Rezaei, Ali
    Abdollahi, Hadi
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (39) : 90243 - 90255
  • [49] An environmentally friendly method for extraction of cobalt and molybdenum from spent catalysts using deep eutectic solvents (DESs)
    Ehsan Ebrahimi
    Hassan Safari
    Mohammad Rezaee
    Ali Rezaei
    Hadi Abdollahi
    Environmental Science and Pollution Research, 2023, 30 : 90243 - 90255
  • [50] Hydrothermal liquefaction of de-oiled Jatropha curcas cake using Deep Eutectic Solvents (DESs) as catalysts and co-solvents
    Alhassan, Yahaya
    Kumar, Naveen
    Bugaje, Idris M.
    BIORESOURCE TECHNOLOGY, 2016, 199 : 375 - 381