Mesoporous silica modified alumina improves pressure stability of supported ionic liquid membranes

Supported liquid membranes (including those containing ionic liquids) offer the opportunity for high selectivity for a target gas imparted by the properties of the functional liquid or liquid mixture, along with high flux resulting from gas permeation through a liquid rather than a solid. One disadvantage of supported liquid membranes is limitations on the transmembrane pressure (TMP) they can sustain. Liquids held in the pores of the support by capillary forces are prone to "blow-out" at relatively modest TMP values. Here, we modify anodic aluminum oxide (AAO) membranes with uniformly sized 6-8 nm diameter cylindrical silica mesopores to improve the blow-out TMP. This modification increases the feasible TMP for various ionic liquids from 4 bar to more than 20 bar. Additionally, the liquid in the membrane at depths where the AAO membrane has not been modified (i.e., greater than a few microns) is expelled from the large pores, reducing the effective thickness of the liquid in the membrane and increasing permeance. This approach is analogous to asymmetric polymeric membranes, which are the standard of the commercial membrane industry. These findings open up the opportunity for investigation and use of supported liquid membranes at much higher TMPs than has been previously possible.