Lanthanide hydrogels with tunable circularly polarized luminescence (CPL) via supramolecular chirality induction

被引:1
|
作者
Laishram, Raju [1 ,2 ,4 ]
Sarkar, Souvik [1 ,2 ]
Maitra, Uday [3 ]
George, Subi J. [1 ,2 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, New Chem Unit, Bangalore 560064, India
[2] Jawaharlal Nehru Ctr Adv Sci Res JNCASR Jakkur, Sch Adv Mat, Bangalore 560064, India
[3] Indian Inst Sci, Dept Organ Chem, Bengaluru, India
[4] Manipur Univ, Dept Chem, Indo Myanmar Road, Imphal 795003, Manipur, India
关键词
ASSEMBLIES; DICHROISM;
D O I
10.1039/d4tc03257h
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lanthanide-derived materials are promising candidates for efficient circularly polarized luminescence (CPL) with a high dissymmetry factor (g(lum)). However, synthesizing chiral ligands in lanthanide-based designs remains challenging. In this context, we present a simpler, modular approach using 'supramolecular chirality induction' and non-covalent sensitization to create soft hydrogel materials with tunable CPL emission and a remarkably high g(lum) of 2 x 10(-2).
引用
收藏
页码:15418 / 15422
页数:5
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