Emergent properties from dynamicity in biomimetic coordination complexes

被引：0

作者：

Griffin, Paul J. ^{[1
]}

Olshansky, Lisa ^{[1
,2
,3
,4
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[2] Univ Illinois, Ctr Biophys & Quantitat Biol, Urbana, IL 61801 USA

[3] Univ Illinois, Mat Res Lab, Urbana, IL 61801 USA

[4] Univ Illinois, Beckman Inst Adv Sci & Technol, Urbana, IL 61801 USA

来源：

TRENDS IN CHEMISTRY | 2024年 / 6卷 / 08期

关键词：

D O I：

10.1016/j.trechm.2024.04.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Many biological metallocofactors exist in dynamic equilibria of electronic and/or structural isomeric forms. Developing metal complexes that mimic this type of dynamicity, we repeatedly observe the emergence of new properties beyond an average of those of the two isomeric forms. These findings suggest that intrinsic conformational dynamicity within metalloprotein active sites may play functional roles in mediating catalysis.

引用

页码：424 / 427

页数：4

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