Pyrene-Based Organic Photoredox Catalysts for Carbon-Carbon Bond-Forming Reactions: Reductive Coupling of Aromatic Carbonyl and Imine Compounds

被引：1

作者：

Okamoto, Shusuke ^{[1
]}

Nagai, Daisuke ^{[1
]}

机构：

[1] Univ Shizuoka, Sch Food & Nutr Sci, Shizuoka 4228526, Japan

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 36期

关键词：

ELECTRON-TRANSFER; PERYLENE; ARYL; DRIVEN; PHOTOCATALYST; DERIVATIVES; COMPLEXES; ALDEHYDES;

D O I：

10.1021/acs.orglett.4c02845

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metal-free photoredox catalysts built upon a pyrene core were developed for carbon-carbon bond-forming reactions. Among these catalysts, a pyrene derivative containing a urea moiety effectively facilitated the reductive coupling of aromatic carbonyl and imine compounds under blue LED irradiation. This process provided the corresponding vicinal diols and diamines in good yields.

引用

页码：7718 / 7722

页数：5

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