Superhydrophobic photothermal coating comprising SiO2-grafted 2-grafted Fe3O4 3 O 4 and Ag decorated reduced graphene for anti-icing and de-icing

Considering the current challenges associated with fossil fuel scarcity and ice accumulation on solid surfaces, we propose a sustainable strategy that utilizes solar energy for ice formation, using a superhydrophobic coating possessing photothermal capabilities to tackle the challenges of icing and de-icing. We have successfully integrated the Fe3O4@SiO2@FAS/Ag-rGO 3 O 4 @SiO 2 @FAS/Ag-rGO composites into an epoxy matrix to create a photothermal super- hydrophobic coating. The innovative coating boasts outstanding super-hydrophobicity with a water contact angle of 153.8 degrees, degrees , resulting in a 60 mu L water droplet experiencing a freezing delay of 1498 s at-20 degrees C ambient conditions, which is longer than that of pure EP coating. Additionally, the coating exhibits an impressive photothermal effect, raising the surface temperature to 58.8 degrees C under 1 sun. The coating also demonstrates rapid deicing capabilities, clearing ice in just 120 s under 40 mW/cm2. 2 . By leveraging the light-trapping effect, utilizing the plasma resonance of silver, and incorporating a high surface roughness micro-nano hierarchical structure, the coating achieves exceptional photothermal conversion efficiency and anti-icing performance. Moreover, the coating's chemical and mechanical durability enhance its practicality and potential utility across various applications. In conclusion, this innovative superhydrophobic coating with photothermal properties offers a promising solution for various practical applications such as anti-icing and de-icing.