Unusual condensation of acetone giving h 3-allyl ligand in the [Pd(h3-C6H9O)(μ-Cl)]2 complex

被引：0

作者：

Efimenko, Inessa A. ^{[1
]}

Kubasov, Alexey S. ^{[1
]}

Ivanova, Nina A. ^{[1
]}

Erofeeva, Olga S. ^{[1
]}

Demina, Ludmila I. ^{[2
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Russian Acad Sci, AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 05期

关键词：

acetone condensation; r1; ligand; one-step reaction; Pd;

D O I：

10.1016/j.mencom.2024.09.040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-step reaction was discovered giving the h 3-allyl complex [Pd(h3-C6H9O)(mu -Cl)]2. h 3-C 6 H 9 O)(mu -Cl)] 2 . The formation of the substituted h 3-allyl ligand in the complex occurs as a result of the condensation of acetone at room temperature in a solution containing [Pd(PhCN)2Cl2] 2 Cl 2 ] and organic acids. The structure of the resulting Pdii ii complex was determined by single crystal X-ray diffraction analysis.

引用

页码：748 / 750

页数：3

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