London Clay;
kaolin;
low-grade bauxite;
belite-ye'elimite-ferrite cements;
hydration;
compressive strength;
UN SDG 13;
RAW MIX DESIGN;
EARLY HYDRATION;
CHEMISTRY;
WATER;
D O I:
10.1680/jadcr.23.00239
中图分类号:
TU [建筑科学];
学科分类号:
0813 ;
摘要:
London Clay (LC) is generated in significant quantities from major infrastructure development projects within and around London. Excavated LC spoils are typically landfilled or used for landscaping purposes with minimal value. This study investigates the feasibility of producing belite-ye'elimite-ferrite (BYF) cements using London Clay (LC) in combination with kaolin or low-grade bauxite. Six cement clinkers with varying compositions were synthesised at 1300 degrees C. The phase composition of the synthesised clinkers was quantified using XRD coupled with Rietveld refinement. The hydration behaviour, phase assemblage evolution, and mechanical performance of the cements were examined using isothermal calorimetry, XRD, TGA, and compressive strength testing respectively, up to 90 days of curing. It is demonstrated that LC can be used either on its own or with kaolin or low-grade bauxite to produce BYF cements with a wide range of composition: 31 to 64 wt.% belite, 9.3 to 27 wt.% ye'elimite and 2.1 to 31% ferrite. The use of LC as the sole alumina source resulted in low compressive strength at early stages. Nevertheless, the strength developed over time, reaching 27.8 MPa at 90 d (0.5 w/b). Possible approaches to develop LC further for producing viable BYF cements are discussed.
机构:Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Lv, Minwang
Yang, Lu
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Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R ChinaWuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Yang, Lu
Wang, Fazhou
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Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R ChinaWuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Wang, Fazhou
Hu, Shuguang
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机构:Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Hu, Shuguang
Zhong, Haoxuan
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机构:Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Zhong, Haoxuan
Zhang, Mai
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机构:Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
Zhang, Mai
He, Jianhui
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机构:Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China